扁桃酸类凝胶因子的合成及其多重刺激响应性能研究  

Synthesis of Mandelic Acid-derived Gelators and Their Multiple Stimuli-responses

作　　者：何鸿达 孙岩 张艺杰 刘笛 张欣[1] HE Hongda;SUN Yan;ZHANG Yijie;LIU Di;ZHANG Xin(College of Chemistry and Materials Science,Hebei Normal Universty,Hebei Key Laboratory of Organic Functional Molecules,Hebei Shijiazhuang 050024,China)

机构地区：[1]河北师范大学化学与材料科学学院,河北省有机功能分子重点实验室,河北石家庄050024

出　　处：《河北师范大学学报（自然科学版）》2021年第2期160-168,共9页Journal of Hebei Normal University：Natural Science

基　　金：国家自然科学基金(21502040);河北省自然科学基金(B201620511)。

摘　　要：设计合成了一系列扁桃酸类凝胶因子,研究发现C15-Try-Mac-N16在多种有机溶剂中表现出良好的凝胶性能,并且此凝胶因子在乙腈中形成的凝胶可通过凝胶崩塌的形式,对一些金属离子(如铁和铜离子)、阴离子(如氟离子)、硫化物及酸碱表现出可视性的传感能力.A series of mandelic acid-derived gelators were designed and synthesized in this paper.Study on the gelation ability of the compounds indicated that C15-Try-Mac-N16 showed good gelation behaviors in various organic solvents.Furthermore,the gels prepared from acetonitrile with this gelator could be used to visually recognize some metal cations(iron and copper ions),fluoride ion,sulfides,and acid/base,via gel collapse.

关 键 词：扁桃酸类凝胶因子 金属离子 氟离子 可视性传感 

分 类 号：O62[理学—有机化学]