Enhanced thermoelectric properties of Zintl phase YbMg_(2)Bi1.98 through Bi site substitution with Sb  

作　　者：Jing Wang Muchun Guo Jianbo Zhu Dandan Qin Fengkai Guo Qian Zhang Wei Cai Jiehe Sui 

机构地区：[1]National Key Laboratory for Precision Hot Processing of Metals,Harbin Institute of Technology,Harbin,150001,China [2]Department of Materials Science and Engineering,Harbin Institute of Technology,Shenzhen,Shenzhen,518055,China

出　　处：《Journal of Materials Science & Technology》2020年第24期189-194,共6页材料科学技术（英文版）

基　　金：supported financially by the National Natural Science Foundation of China(Nos.51771065 and 51871082)。

摘　　要：Benefiting from the unique"Phonon-Glass,Electron-Crystal"(PGEC)characteristic,Zintl phases have been considered as a kind of promising thermoelectric materials.For the typical AM2X2 compounds with the CaAl2Si2-type structure,YbMg_(2)Bi2 has shown competitive thermoelectric performance recently.Nevertheless,the optimization of YbMg_(2)Bi2 compounds is primarily focused on the substitution on Yb or Mg site.Herein,the Bi site is substituted by isoelectric Sb and the effect on the thermoelectric transport behavior is investigated.The partial substitution reduces the carrier concentration and induces the lattice deformation caused by the different atomic radius and mass between Bi and Sb,further leading to the decreased power factor and thermal conductivity.Fortunately,the reduction extent of the thermal conductivity outperforms that of power factor.Finally,the Sb substitution successfully results in a better thermoelectric performance compared with that of the pristine YbMg_(2)Bi1.98.Especially,the calculated energy conversion efficiency(a)of YbMg_(2)Bi1.88Sb0.1 which also possesses a relatively high output power density reaches the maximum value of 9.8% when Th=873 K,and Tc=300 K,respectively.This work demonstrates that the idea of substitution on anionic site should be a new strategy to achieve better ZT values for AM2X2 compounds.

关 键 词：Zintl phase YbMg_(2)Bi2 Anionic substitution Thermoelectric properties 

分 类 号：TB34[一般工业技术—材料科学与工程]