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作 者:Jianqiang Chen Lingwei Wu Jie Wu
机构地区:[1]School of Pharmaceutical and Materials Engineering Eflnstitute for Advanced Studies,Taizhou University,Taizhou 318000,China [2]State Key Laboratory of Organometallic Chemistry,Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences,Shanghai 200032,China
出 处:《Chinese Chemical Letters》2020年第12期2993-2995,共3页中国化学快报(英文版)
基 金:the National Natural Science Foundation of China(Nos.21871053 and 21532001);the Leading Innovative and Entrepreneur Team Introduction Program of Zhejiang(No.2019R01005)。
摘 要:The deconstructive reorganization strategy for the synthesis of benzene-containing products from the kojic acid-and maltol-derived alkynes has been recently reported.In this strategy,kojic acid and maltol are analogous to the"Transformers",which can transform into benzofurans and benzaldehydes via annulation reactions.Under the synthetic standpoint,this deconstructive reorganization strategy features high atom economy,innate scalability and functional group tolerance.In the near future,we believe that this unique method will be widely investigated a nd other novel transformations of kojic acid and maltol will be discovered.
关 键 词:Kojic acids Maltols REARRANGEMENT Deconstructive reorganization BENZOFURANS
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