稀土超分子配合物研究进展  

Progress on Rare-Earth Supramolecular Complexes

作　　者：杨倩倩 李晓磊 唐金魁[1,2] Yang Qianqian;Li Xiaolei;Tang Jinkui(Stale Key Laboralory of Rare Earth Resource Utilisation,Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,Changchun 130022,China;School of Applied Chemistry and Engineering,Unirersity of Science and Technolo gy of China,Hefei 230026,China)

机构地区：[1]中国科学院长春应用化学研究所,稀土资源与利用国家重点实验室,吉林长春130022 [2]中国科学技术大学应用化学与工程学院,安徽合肥230026

出　　处：《中国稀土学报》2021年第1期128-142,共15页Journal of the Chinese Society of Rare Earths

基　　金：国家自然科学基金面上项目(21871247)资助。

摘　　要：超分子化学作为"广义上的配位化学",是一个充满活力的领域。基于配位自组装,设计合成具有不同拓扑结构和功能特性的超分子配合物是超分子化学的研究重点。基于稀土元素构筑的超分子配合物不仅丰富了配位超分子体系,也是制备功能性配合物的核心内容。主要从拓扑结构调控、结构修饰和功能特性等方面综述了螺旋、格子、环状和笼状等稀土超分子配合物的最新研究进展,探讨了配体设计在超分子自组装过程中的作用,旨在为稀土超分子化合物的设计与调控提供新思路。Supramolecular chemistry, as an "extension of coordination chemistry", is a vigorous field. The design and synthesis of supramolecular complexes with different topologies and functional properties based on coordination self-assembly are one of the emphases of supramolecular chemistry. Constructing rare-earth supramolecular complexes are core content of the synthesis of functional complexes, which also pushes the frontier of supramolecular system. This article reviewed the up-to-date research progress of rare earth supramolecular complexes, such as helixes, grids, rings, and cages, in terms of structural modification and properties. Additionally, the role of ligand design in the assemblies was discussed. We are aiming to provide ideas for the design and modulation of rare-earth supramolecular complexes.

关 键 词：超分子配合物 稀土 螺旋 格子 环状 笼状 

分 类 号：O641.3[理学—物理化学]