异腈单体的聚合及在功能高分子材料制备中的应用  

Isocyanide-Based Polymerizations and Their Generated Functional Polymers

作　　者：程天宇[1] 秦安军[1] 唐本忠[1,2] Tianyu Cheng;Anjun Qin;Ben Zhong Tang(State Key Laboratory of Luminescent Materials and Devices,Guangdong Provincial Key Laboratory of Luminescence from Molecular Aggregates,SCUT-HKUST Joint Research Institute,AIE Institute,Center for Aggregation-Induced Emission,South China University of Technology(SCUT),Guangzhou 510640,China;Department of Chemistry,Hong Kong Branch of Chinese National Engineering Research Centre for Tissue Restoration and Reconstruction,the Hong Kong University of Science&Technology(HKUST),Hong Kong 999077,China)

机构地区：[1]华南理工大学发光材料与器件国家重点实验室广东省大湾区华南理工大学聚集诱导发光高等研究院广东省分子聚集发光重点实验室聚集诱导发光研究中心,广东广州510640 [2]香港科技大学化学系国家人体组织功能重建工程技术研究中心香港分中心,香港999077

出　　处：《高分子材料科学与工程》2021年第1期169-181,共13页Polymer Materials Science & Engineering

基　　金：国家自然科学基金资助项目(21788102,21525417);广东省自然科学基金资助项目(2019B030301003,2016A030312002);香港创新及科技基金(ITC-CNERC14S01)。

摘　　要：作为一类重要的三键单体,异腈单体的聚合可产生含氮原子的新型聚合物,并赋予其特殊的功能和应用,因而这一领域的研究引起了越来越多的关注并已经取得了长足的进展。但是,目前鲜有文献对该领域进行较全面的综述。本专论较系统地总结了近年来基于异腈单体的单组分、双组分以及多组分聚合反应,并较详细介绍了其在制备光电和生物等功能高分子材料方面的应用,最后对其未来可能的发展方向进行了展望。Thanks to the highly efficient of isocyanide-based organic reaction,the isocyanide-involved polymerizations have also been developed and used to prepare nitrogen-containing novel polymers with remarkable functions have been constructed.At present,the new polymerizations based on isocyanide have been reported continuously,but few articles have been published to review these new polymerizations.In this review,we briefly summarized the recent progresses in the development of isocyanide-involved polymerizations and their applications in preparation of functional polymers.The polymerizations were classified by the number of monomers,i.e.single component,double component and multicomponent polymerizations.Moreover,the properties and applications of the polymeric materials were also introduced in detail.It is anticipated that with the efforts paid by the polymer scientists,more efficient isocyanide-involved polymerizations will be established and new applications of the resultant polymeric materials will be developed.

关 键 词：异腈单体 聚合反应 功能高分子材料 

分 类 号：O631.5[理学—高分子化学]