防毒面具用Zr-MOFs吸附材料研究进展  

Progress on Zirconium-based Metal Organic Frameworks(Zr-MOFs)as Absorptive Materials for Gas Masks

作　　者：周川 杨博[1] 杨光[1] 杨德瑞[1] 杨小兵 ZHOU Chuan;YANG Bo;YANG Guang;YANG Derui;YANG Xiaobing(State Key Laboratory of NBC Protection for Civilian,Research Institute of Chemical Defense,Beijing 100191,China)

机构地区：[1]防化研究院,国民核生化灾害防护国家重点实验室,北京100191

出　　处：《材料导报》2021年第5期5140-5146,共7页Materials Reports

基　　金：国民核生化灾害防护国家重点实验室基金。

摘　　要：锆基金属有机骨架(Zr-based metal organic frameworks,Zr-MOFs)材料是由金属锆离子或金属锆簇与多齿有机配体自组装而形成的多孔晶体材料,其优异的稳定性及简单丰富的制备方法使其在有毒气体吸附领域具有广阔的应用前景。本文简述了Zr-MOFs材料的组成及优点,综述了Zr-MOFs作为防毒面具吸附材料对酸性、碱性及中性有毒气体的吸附性能的研究进展,同时展望了其发展前景,指出高效、广谱Zr-MOFs是防毒面具吸附材料研究的重点方向。Zr-based metal organic frameworks(Zr-MOFs)are a class of interesting three-dimensional crystalline porous materials constructed by coordination of zirconium metal ions or metal ion clusters with multidentate organic ligands,which make them have a great application prospect in the field of toxic gases adsorption due to the superior stability and ease and versatility of synthesis.In this article,the composition and advantages of Zr-MOFs are introduced.Progress on the adsorption performance of acidic,alkaline and neutral toxic gases by Zr-MOFs adsorption materials in gas masks is discussed in detail,separately.An outlook on the future direction of Zr-MOFs as gas mask adsorption materials is made at the same time.Zr-MOFs with high performance and broad-spectrum used in the gas masks are the focus of the adsorption materials in the future research.

关 键 词：多孔介质 Zr-MOFs 防毒面具 吸附 有毒气体 

分 类 号：TB333[一般工业技术—材料科学与工程]