稀土金属配合物催化的烯烃配位聚合中立构规整度的调控  

Stereospecific coordination polymerization of vinyl monomers mediated by rare earth metal complexes

作　　者：武振强 付雪峰 Zhenqiang Wu;Xuefeng Fu(Advanced High Temperature Structural Material Laboratory,AECC Beijing Institute of Aeronautical Material,Beijing 100095,China;National Natural Science Foundation of China,Department of Chemical Sciences,Beijing 100085,China;State Key Lab of Rare Earth Materials Chemistry and Applications,College of Chemistry and Molecular Engineering,Peking University,Beijing 100871,China)

机构地区：[1]中国航发北京航空材料研究院,先进高温结构材料重点实验室,北京100095 [2]国家自然科学基金委员会化学科学部,北京100085 [3]稀土材料化学及应用国家重点实验室,北京大学化学与分子工程学院,北京100871

出　　处：《中国科学：化学》2020年第11期1654-1671,共18页SCIENTIA SINICA Chimica

基　　金：国家自然科学基金(编号:20801002)资助项目。

摘　　要：聚合物的立构规整度会显著影响其物理化学性质.如何调控聚合物的立构规整度,进而实现对聚合物性质的调控,一直是高分子合成化学中的研究热点和难点.本文综述了近年来稀土金属配合物催化的配位聚合中调控聚合物立构规整度的最新研究进展,介绍了苯乙烯、取代苯乙烯、2-乙烯基吡啶等单烯烃为单体时,通过优化配合物结构和反应条件实现对聚合物立构规整度的调控.此外,本文还对有待进一步深入研究和探索的问题提出了建议和展望.The stereospecific polymerization is one of the most critical topics in polymer sciences,due to the significant influence of tacticity on the properties of polymers.This review summarizes recent progress in stereospecific coordination polymerization mediated by rare earth metal complexes.The stereospecific coordination polymerization is achieved by optimizing the structures of ligands,the rare earth metal ions,and the polymerization conditions,while styrene,polar substituted styrenes,2-vinylpyridine and other olefins are used as monomers.The properties of resulting polymers are significantly influenced by the structure of monomers,and the tacticity of polymers.

关 键 词：稀土金属配合物 配位聚合 立构规整度 

分 类 号：O641.4[理学—物理化学]