金属有机框架材料在化学战剂降解中的应用研究进展  

Advance on the application of MOFs in the degradation of chemical warfare agent

作　　者：吴遥 张秀玲 习海玲 李从举 Wu Yao;Zhang Xiuling;Xi Hailing;Li Congju(Key Laboratory of Resource-oriented Treatment of Industrial Pollutants,School of Energy and Environmental Engineering,University of Science and Technology Beijing,Beijing 100083;State Key Laboratory of NBC Protection for Civilian,Research Institute of Chemical Defense,Beijing 102205)

机构地区：[1]北京市工业典型污染物资源化处理重点实验室,北京科技大学能源与环境工程学院,北京100083 [2]国民核生化灾害防护国家重点实验室,军事科学院防化研究院,北京102205

出　　处：《化工新型材料》2021年第1期209-213,共5页New Chemical Materials

基　　金：国民核生化灾害防护国家重点实验室基金(SKLNBC2018-15);中央高校基本科研业务费专项资金项目(06500100);国家自然科学基金(51973015,51503005,21274006);北京市科技北京百名领军人才工程(Z161100004916168)。

摘　　要：化学战剂是一类毒性大、作用速度快、毒性持久、能大规模毒害敌方的化学物质,因为对人体健康和环境存在严重危害,所以开发能快速降解化学战剂的材料在军事和民用领域具有重要意义。金属有机框架材料是一种由金属离子或金属离子簇与有机配体通过配位方式形成的多孔晶体材料,具有比表面积大、孔隙率高、结构可调、易于修饰等优点,优异的吸附性能和催化性能使得金属有机框架材料在化学战剂降解领域具有广阔的应用前景。综述了近年来金属有机框架材料在降解化学战剂方面的研究进展,并展望了其未来的发展前景。Chemical warfare agents are a class of chemicals with high toxicity,fast action,long-lasting toxicity,and large-scale poisoning of the enemy.Because of its serious harm to human health and environment,the development of materials capable of rapidly degrading chemical warfare agents has great significance in both military and civilian applications.Metal-organic frameworks(MOFs)are porous crystalline materials comprised of metal nodes/clusters and organic linkers,have the advantages of high surface area,high porosity,adjustable structure and easy to modification.MOFs has a promising application in degradation chemical warfare agents due to its superior adsorption and excellent catalytic performance.The advanced application of MOFs to degrade chemical warfare agents was reviewed.Moreover,the future development was also discussed.

关 键 词：化学战剂 金属有机框架 异相催化反应 单线态氧 

分 类 号：O614[理学—无机化学]