羟基香茅醛肟及其烷基醚的合成与除草活性  

Synthesis and Herbicidal Activity of Hydroxycitronellal Oxime and Its Alkyl Ethers

作　　者：彭云 肖转泉[2] 廖圣良[1] 范国荣[1] 陈尚钘[1] 王宗德[1] PENG Yun;XIAO Zhuanquan;LIAO Shengliang;FAN Guorong;CHEN Shangxing;WANG Zongde(College of Forestry,Jiangxi Agricultural University,East China Woody Fragrance and Flavor Engineering Research Center of National Forestry and Grassland Administration,Camphor Engineering Research Center of NFGA/Jiangxi Province,Nanchang 330045,China;College of Chemistry and Chemical Engineering,Jiangxi Normal University,Nanchang 330027,China)

机构地区：[1]江西农业大学林学院,国家林业草原木本香料(华东)工程技术研究中心,国家林业草原/江西省樟树工程技术研究中心,江西南昌330045 [2]江西师范大学化学化工学院,江西南昌330027

出　　处：《生物质化学工程》2021年第2期55-59,共5页Biomass Chemical Engineering

基　　金：国家重点研发计划资助项目(2017YFD0600704);国家自然科学基金资助项目(31660178)。

摘　　要：将羟基香茅醛(1)与盐酸羟胺反应合成羟基香茅醛肟(2),再与溴代烷反应制得4种羟基香茅醛肟烷基醚(3a~3d),用GC-MS、IR和NMR对产物结构进行了表征。采用平皿法测定了羟基香茅醛肟及其烷基醚在不同浓度下对一年生黑麦草生长的抑制作用,结果表明:化合物3b(0.31 mmol/L)、化合物3c(0.63 mmol/L)、化合物3d(2.50 mmol/L)对一年生黑麦草根的生长抑制率高于阳性对照敌草隆(10 mmol/L)对黑麦草根的抑制率(94.1%);化合物3b(0.31 mmol/L)、3d(0.31 mmol/L),化合物3c(0.63 mmol/L)对一年生黑麦草茎的生长抑制率高于敌草隆(10 mmol/L)对黑麦草茎的抑制率(88.10%)。Hydroxycitronellal oxime(2)was synthesized from hydroxycitronellal(1)and hydroxylammonium chloride,and then reacted with bromoalkanes to give 4 hydroxycitronellal oxime alkyl ethers(3a-3d).The structures of the products were characterized by GC-MS,IR and NMR.The inhibitory effect of oxime and its alkyl ethers on the growth of annual ryegrass in different concentrations were determined by the plate method.The results showed that when the concentration of 3b was 0.31 mmol/L,the concentration of 3c was 0.63 mmol/L and the concentration of 3d was 2.50 mmol/L,the growth inhibition rate of the annual ryegrass roots were higher than that of diuronat the concentration of 10 mmol/L(94.1%).When the concentration of 3b and 3d were 0.31 mmol/L and the concentration of 3c was 0.63 mmol/L,the inhibitory rate on the growth of annual ryegrass stemswere higher than that of diuron at the concentration of 10 mmol/L(88.10%).

关 键 词：羟基香茅醛 羟基香茅醛肟 肟醚 合成 除草活性 

分 类 号：TQ35[化学工程]