Luminescence Regulation of Silver-Thiolate Clusters Protected by 1,2-Dithiolate-o-carborane  

作　　者：Li-Juan Liu Thomas C.W.Mak Shuang-Quan Zang 

机构地区：[1]College of Chemistry,Zhengzhou University,Zhengzhou,Henan 450001,China [2]Department of Chemistry,The Chinese University of Hong Kong,Shatin,New Trritries,Hong Kong SAR,China

出　　处：《Chinese Journal of Chemistry》2021年第1期81-86,共6页中国化学（英文版）

基　　金：This work was supported by the National Science Fund for Distinguished Young Scholars(No.21825106);the National Natural Science Foundation of China(No.21671175);the Program for Innovative Research Team(in Science and Technology)in Universities of Henan Province(No.19IRTSTHN022)and Zhengzhou University.

摘　　要：Engineering the surface of the metal clusters with the core structure maintained and tuning their luminescence in a wide range is still a challenge in the nanomaterial research.We modified six mono-pyridyl ligands with different electronic effects(conjugation effect or induction effect)on a superatomic silver cluster[Ag_(14)(C_(2)B_(10)H_(10)S_(2))_(6)(CH_(3)CN)_(8)](denoted as Ag_(14))through in situ site-specific surface engineering.

关 键 词：Silver clusters Surface modification 1 2-Dithiolate-o-carborane LUMINESCENCE 

分 类 号：O61[理学—无机化学]