超高温耐热含能材料研究进展  

Research Progress in Ultra-Temperature Heat-Resistant Energetic Materials

作　　者：刘宁[1] 肖川 张倩[1] 卢先明[1] 王伯周[1] LIU Ning;XIAO Chuan;ZHANG Qian;LU Xianming;WANG Bozhou(Xi’an Modern Chemistry Research Institute, Xi’an 710065, China;China Ordnance Science Research Institute, Beijing 100089, China)

机构地区：[1]西安近代化学研究所,西安710065 [2]中国兵器科学研究院,北京100089

出　　处：《兵器装备工程学报》2021年第1期115-121,共7页Journal of Ordnance Equipment Engineering

基　　金：国家自然科学基金项目(21703168)。

摘　　要：针对超高温耐热含能材料在高超音速武器、宇航工程和超深井爆破领域的重要应用价值,对国内外典型超高温耐热含能材料PYX、TACOT、NONA以及新型材料TNBP、NBTTP、TKX-55等的最新研究进展进行了综述。总结了每种材料的合成路线、密度、爆轰性能、耐热性能及应用优缺点,并进行了对比分析。结果表明,耐热含能材料的重点发展方向是加强新型桥连和氮杂稠环耐热含能骨架的结构设计和构建研究,同时对性能优异的材料开展合成新工艺和工程化制备研究,推动超高温耐热含能材料的进一步应用。The ultra-temperature heat-resistant energetic materials have great value in the areas of hypersonic weapon,aerospace engineering and ultra-deep well blasting.The latest research progress of typical ultra-temperature heat-resistant energetic materials PYX,TACOT,NONA and new materials TNBP,NBTTP,TKX-55 in China and abroad were reviewed.The synthetic route,density,energetic performances,thermal stabilities,advantages and disadvantages of each materials were summarized and analyzed.It is suggested that the direction of development of heat-resistant energetic materials are to strengthen the design and construction of new coupling and fused aza-polycyclic heat-resistant energetic structures,to strengthen the research of new preparation process and manufacturing technology of materials with best performances,and to promote the application of ultra-temperature heat-resistant energetic materials.The number of attached references is 42.

关 键 词：有机合成 含能材料 耐热 热分解温度 能量密度 

分 类 号：TJ55[兵器科学与技术—军事化学与烟火技术]