树脂基水合氧化铈复合材料深度去除污水中磷酸盐  

Deep Removal of Phosphate in Wastewater by Resin-based Hydrated Cerium Oxide Composite

作　　者：姜其 岑渝华 朱玥 施如艳 陆晨阳 史新星 杨文澜[1] JIANG Qi;CENYu-hua;ZHU Yue;SHI Ru-yan;LU Chen-yang;SHI Xin-xing;YANG Wen-lan(College of Environmental Science and Engineering,Yangzhou University,Yangzhou 225127,China)

机构地区：[1]扬州大学环境科学与工程学院,江苏扬州225127

出　　处：《中国给水排水》2021年第3期99-103,共5页China Water & Wastewater

基　　金：国家自然科学基金资助项目(52070160);江苏省产学研合作项目(BY2020454);江苏省环境工程重点实验室开放基金资助项目(KF2018-004);江苏省大学生实践创新训练计划(201911117112Y);江苏省研究生实践创新计划项目(XSJCX19091)。

摘　　要：通过"前驱体导入-原位沉积"的工艺路线,将水合氧化铈(HCO)纳米颗粒负载入强碱阴离子交换树脂(SAE)孔道内,制得复合纳米吸附剂HCO@SAE并用于污水中磷酸盐的深度去除。试验结果表明:与其母体材料SAE、粉末活性炭(PAC)和大孔吸附树脂XAD-4相比,HCO@SAE具有最佳的磷酸盐吸附性能。溶液pH值对HCO@SAE吸附磷酸盐的性能有较大影响,且在中性条件下可获得最大的磷酸盐吸附量(30.96 mgP/g)。得益于负载HCO纳米颗粒对磷酸盐的专属内配位络合作用,HCO@SAE能够在共存高浓度竞争离子的条件下实现对磷酸盐的选择性吸附。采用NaOH-NaCl混合溶液作为脱附剂可实现对吸附饱和HCO@SAE的高效再生,再生后吸附性能保持稳定,从而实现多批次循环吸附操作。Hydrated cerium oxide(HCO)nanoparticles were loaded into strong-base anion exchanger(SAE)through the process of"precursor lead-in and in-situ deposition",and a composite nano adsorbent HCO@SAE was prepared and used for deep removal of phosphate in wastewater.HCO@SAE exhibited the best phosphate removal performance as compared to its host materials:SAE,powder activated carbon(PAC)and macroporous polystyrene resin(XAD-4).The p H value of the solution had a great influence on phosphate adsorption performance of HCO@SAE,and the maximum phosphate adsorption capacity(30.96 mgP/g)could be obtained at neutral pH.Benefiting from the inner-sphere complexation between phosphate and the loaded HCO nanoparticles,HCO@SAE was capable of selective adsorbing phosphate even coexisting with high levels of other competing anions.More attractively,the exhausted HCO@SAE could be effectively regenerated by using NaOH-NaCl binary solution as the desorbent.After regeneration,its adsorption performance remained stable,thus realizing multi-batch cyclic adsorption operation.

关 键 词：纳米复合吸附剂 水合氧化铈 磷 选择性去除 

分 类 号：TU992[建筑科学—市政工程]