硅氧烷改性苯并噁嗪材料的合成及研究进展  

Synthesis and Research Progress of Benzoxazines Modified by Siloxane

作　　者：刘秋君 安晨 孙安邦 单雅娟 魏增岳 李强 董志超 张迪 曾庆铭 卢海峰[1,2] LIU Qiu-jun;AN Chen;SUN An-bang;SHAN Ya-juan;WEI Zeng-yue;LI Qiang;DONG Zhi-chao;ZHANG Di;ZENG Qing-ming;LU Hai-feng(School of Chemistry and Chemical Engineering,Shandong University,Jinan 250100,Shandong;Key Laboratory of Special Function Aggregate Materials,Ministry of Education,Shandong University,Jinan 250100,Shandong;Shandong Baolongda Industrial Group Co.,Ltd.,Weifang 262600,Shandong)

机构地区：[1]山东大学化学与化工学院,济南250100 [2]山东大学特种功能聚集体材料教育部重点实验室,济南250100 [3]山东宝龙达实业集团有限公司,山东潍坊262600

出　　处：《有机硅材料》2021年第2期57-63,共7页Silicone Material

基　　金：山东省重点研发计划(2017CXGC1113);山东省重大科技创新工程项目(2019JZZY010503);山东省自然科学基金面上项目(ZR2017MB033)。

摘　　要：苯并噁嗪树脂存在脆性大、成膜性低、开环温度过高以及与复合材料的相容性差等缺点,可用硅氧烷对其进行改性。概括了硅氧烷改性苯并噁嗪的方法及硅氧烷的引入对苯并噁嗪性能的影响;综述了硅氧烷改性苯并噁嗪的研究进展(作为紫外光固化、热致性形状记忆及人体运动检测材料),并展望了未来硅氧烷改性苯并噁嗪的发展方向。The benzoxazine resin is modified by siloxane because of its disadvantages of high brittleness,low film formation,high ring-opening temperature and poor compatibility with the composite materials.The methods of siloxane-modified benzoxazine and the effect of siloxane on the properties of benzoxazine are summarized.Furthermore,this paper summarizes the trend of siloxane-modified benzoxanine,such as UV curing,thermally induced shape memory and human motion detection materials.Finally,the future development of siloxane modified benzoxazine is prospected.

关 键 词：苯并噁嗪 硅氧烷 改性 研究进展 

分 类 号：TQ264.1+4[化学工程—有机化工]