A leap forward in sulfonium salt and sulfur ylide chemistry  

作　　者：Rong Fan Chen Tan Yongguo Liu Yun Wei Xiaowen Zhao Xinyuan Liu Jiajing Tan Hiroto Yoshida 

机构地区：[1]Department of Organic Chemistry,Faculty of Chemistry.Beijing University of Chemical Technology(BUCT),Beijing 100029,China [2]Department of Applied Chemistry,Graduate School of Engineering.Hiroshima University,Higashi-Hiroshim,739-8527,Japan [3]Beijing Key Laboratory of Flavour Chemistry,Beijing Technology and Business University(BTBU),Beijing 100048,China

出　　处：《Chinese Chemical Letters》2021年第1期299-312,共14页中国化学快报（英文版）

基　　金：the support from the National Natural Science Foundation of China(No.21702013);the Fundamental Research Funds for the Central Universities(Nos.XK1802-6 and buctrc201721)at the BUCT.J;Tan and Y.Liu are thankful for the support from the Open Project Program(No.SPFW2019YB06)of Beijing Key Laboratory of Flavor Chemistry,Beijing Technology and Business University(BTBU)。

摘　　要：Sulfonium salts and sulfur ylides are important S(Ⅳ) motifs,and have displayed many unique reactivities to provide simple,effective,and often stereoselective synthesis toward sulfur containing compounds.Impressive developments have been witnessed within this field during the past several years.In light of the increasing demand of organosulfur compounds across the range of chemical sciences,our aim of this review is to provide a concise overview of recent advances of sulfonium salt and sulfur ylide chemistry.Selected examples are organized in three parts on the basis of their role in organic reactions(reactants,intermediates and catalysts).

关 键 词：SULFONIUM Sulfur ylide REACTANTS INTERMEDIATES CATALYSTS 

分 类 号：TQ266[化学工程—有机化工]