Recent progress on high-pressure and hightemperature studies of fullerenes and related materials  

作　　者：Cuiying Pei Lin Wang 

机构地区：[1]Center for High Pressure Science and Technology Advanced Research(HPSTAR),1690 Cailun Rd.,Pudong District,Shanghai 201203,People’s Republic of China

出　　处：《Matter and Radiation at Extremes》2019年第2期70-83,共14页极端条件下的物质与辐射（英文）

基　　金：This work was mainly supported by National Science Associated Funding(NSAF,Grant No.U1530402);the Natural Science Foundation of China(Grant No.11874076);the Science Challenging Program(Grant No.JCKY2016212A501);the Postdoctoral Science Foundation(2015M572499).

摘　　要：Polymerization of fullerenes is an interesting topic that has been studied for almost three decades.A rich polymeric phase diagram of C60 has been drawn under a variety of pressure P and temperature T conditions.Knowledge of the targeted preparation and structural control of fullerene polymers has become increasingly important because of their utility in producing novel fullerenebased architectures with unusual properties and potential applications.This paper focuses on the polymeric phases of fullerenes and their derivatives under high P and/or high T.First,the polymerization behavior and the various polymeric phases of C60 and C70 under such conditions are briefly reviewed.A summary of the polymerization process of intercalated fullerenes is then presented,and a synthetic strategy for novel structural and functional fullerene polymers is proposed.Finally,on the basis of the results of recent research,a proposal is made for further studies of endohedral fullerenes at high P.

关 键 词：conditions. POLYMERIC POLYMERIZATION 

分 类 号：O61[理学—无机化学]