Luminescent Lanthanide-titanium-organic Compound Constructed by Tetra-nuclear Ln-Ti Building Units and Diphenylglycolic Acid  

作　　者：CHEN Zi-Bin CHEN Bing-Ben CHENG Jian-Wen 陈子彬;陈炳奔;程建文(Key Laboratory of the Ministry of Education for Advanced Catalysis Materials,Institute of Physical Chemistry,Zhejiang Normal University,Jinhua,Zhejiang 321004,China)

机构地区：[1]Key Laboratory of the Ministry of Education for Advanced Catalysis Materials,Institute of Physical Chemistry,Zhejiang Normal University,Jinhua,Zhejiang 321004,China

出　　处：《Chinese Journal of Structural Chemistry》2021年第2期182-186,146,共6页结构化学（英文）

基　　金：Supported by the NNSF of China(21975224)。

摘　　要：(Under solvothermal conditions with the mixed solvents of C_(2)H_(5)OH and H_(2)O,a new heterometallic lanthanide-titanium-organic compound,[TbTi(μ3-O)(L_(3))(H_(2)O)_(4)]·H_(3)O(1,H_(2)L=diphenylglycolic acid),has been synthesized.Compound 1 exhibits a 3D supramolecular framework by incorporating the tetra-nuclear[Tb_(2)Ti_(2)(μ3-O)2]unit and L^(2-)ligand.Compound 1 shows intense green luminescence.Furthermore,the PXRD,TGA and IR spectra were also studied.)

关 键 词：LANTHANIDE TITANIUM cluster LUMINESCENCE 

分 类 号：O641.4[理学—物理化学] TB34[理学—化学]