基于间苯三酚及其衍生物构筑新型有机多孔材料  

Synthesis of Novel Porous Organic Materials Based on Phloroglucinol and Its Derivatives

作　　者：邓汉林 罗贤升 李志华 赵江颖 黄木华[1] Deng Hanlin;Luo Xiansheng;Li Zhihua;Zhao Jiangying;Huang Muhua(School of Materials Science and EngineeringBeijing Instiute of Technology,Beijing 100081;Gansu Yinguang Chemical Indusry Group Co.,Ltd,Baiyin,Gansu 730900)

机构地区：[1]北京理工大学材料学院,北京100081 [2]甘肃省银光化学工业集团有限公司,甘肃白银730900

出　　处：《有机化学》2021年第2期624-641,共18页Chinese Journal of Organic Chemistry

基　　金：国家自然科学基金(No.21772013);北京市自然科学基金(No.2202049)资助项目.

摘　　要：有机多孔材料凭借其高比表面积、孔道可调性、易功能化修饰和结构多样性等特征,在催化、能源、吸附与分离等多个领域中展现了巨大应用潜力.对多官能度有机化合物单体以及高效聚合反应的巧妙应用,为新型有机多孔材料的创制提供了强有力的工具,成为该领域的研究热点.以C_(3)对称型的间苯三酚及其衍生物为例,综述了其在一系列新型有机多孔材料高效构筑中的最新研究进展.Porous organic materials have found many applications,such as catalysis,energy,adsorption and separation.,owing to the high specific surface area,pore channel tunability,easy functionalization and structural diversity.The careful selection of specific monomers with polyfunctionality and highly efficient polymerization provides powerful tools for creating novel porous organic materials,and it has become a research topic in this field.Herein the latest progress in the efficient construction of novel porous organic materials is reviewed taking C_(3) symmetrical phloroglucinol and its derivatives as examples.

关 键 词：间苯三酚 多孔高分子材料 金属有机框架 共价有机框架 功能化 

分 类 号：O625.312[理学—有机化学] TB383.4[理学—化学]