反应型水性纳米环氧乳化剂的制备及其性能研究  

Preparation and Properties of Reactive Waterborne Nano Epoxy Emulsifier

作　　者：彭军 周如青[2] 张习文 任碧野 PENG Jun;ZHOU Ru-qing;ZHANG Xi-wen;REN Bi-ye(Guangzhou Synthetic Materials Research Institute Co.,Ltd.,Guangzhou 510665,China;Hangzhou Wahaha Group Co.,Ltd.,Machinery&Engineering Department,Hangzhou 310018,China;School of Materials Science and Engineering,South China University of Technology,Guangzhou 510640,China)

机构地区：[1]广州合成材料研究院有限公司,广州510665 [2]杭州娃哈哈集团设备工程部,杭州310018 [3]华南理工大学材料科学与工程学院,广州510640

出　　处：《现代涂料与涂装》2021年第3期1-4,7,共5页Modern Paint & Finishing

摘　　要：研究了反应型水性纳米环氧乳化剂合成中催化剂种类及温度与反应时间、转化率的关系,结果发现:当采用三氧化硼乙醚作为催化剂,添加量0.2%、反应温度90℃、反应时间4h时反应条件最佳;采用PEG-6000为原料,其与E-51物质的量比为1.0:1.2时制得的乳化剂效果最佳。最后,通过红外及核磁对其结构进行了表征。The relationship between the type of catalyst and temperature and the reaction time and conversion rate in the synthesis of reactive waterborne epoxy nano emulsifier was studied by titration of epoxy value with hydrochloric acid-acetone method.It was found that when boron trifluoride ether was used as the catalyst,the addition amount was 0.2%,the reaction temperature was 90℃,and the reaction time was 4 hours.Using PEG-6000 as the raw material,the emulsifier prepared at a molar ratio of 1.0-1.2 to E-51 has the best effect.The structure was characterized by infrared and nuclear magnetic resonance.

关 键 词：环氧树脂 乳化剂 水性 纳米 

分 类 号：TQ630.494[化学工程—精细化工]