三聚氰胺树脂碳基材料在电化学储能中的研究进展  

Research progress of carbon-based materials of melamine resin as precursor in electrochemical energy storage electrode materials

作　　者：王鹏飞 支云飞 陕绍云[1] 苏红莹[1] 邹冉 王守宏 WANG Pengfei;ZHI Yunfei;SHAN Shaoyun;SU Hongying;ZOU Ran;WANG Shouhong(Faculty of Chemical Engineering,Kunming University of Science and Technology,Kunming 650504,Yunnan,China)

机构地区：[1]昆明理工大学化学工程学院,云南昆明650504

出　　处：《精细化工》2021年第3期454-463,共10页Fine Chemicals

基　　金：国家自然科学基金项目(21766016);云南省“万人计划”基金项目(YNWR-QNBJ-2018-198);昆明市科学技术局科技计划基金项目(2019-1-G-25318000003480);倪永浩院士工作站项目(2019IC002);云南省基础研究计划青年项目(KKSQ202005001)。

摘　　要：电极材料是影响电化学储能系统性能的主要因素。目前,对电极材料性能改善的研究主要集中于结构的优化和杂原子的引入两个方面。以三聚氰胺树脂为前驱体制备的碳基材料凭借其丰富的孔道结构和高含量的氮原子掺杂双重优势,在电化学储能设备的电极材料的应用中表现出高电容性能和出色的循环能力。该文从活化法、模板炭化法、混合聚合物炭化法等孔道控制工艺,探讨了孔道结构对于材料性能的影响。针对当前主流研发的电池和超级电容器,对以三聚氰胺树脂为原料制备的碳基材料展开综述,并分析其研究现状与发展趋势。Electrode materials are a main factor affecting electrochemical energy storage system performance.At present,the research on its performance improvement is focused on the structural optimization and the introduction of heteroatom.Carbon-based materials,which are prepared by melamine resin as precursor,have excellent capacitive performance and recycle ability in the application of electrode materials of electrochemical energy storage due to their double advantages of abundant porous structure and nitrogen atoms doping.The influence of porous structure on its performance from the porous control method such as activation method,template-carbonization method,and mixed polymer carbonization method is discussed.Meanwhile,the carbon-based materials used as electrode materials for current batteries and super capacitors,which are prepared by using melamine resin as precursor are reviewed.The research status and development trend are also analyzed.

关 键 词：三聚氰胺树脂 电化学储能 碳基电极材料 二次电池 超级电容器 

分 类 号：O613.71[理学—无机化学]