生物质炭基材料在有机催化转化中的应用  

Biomass-derived carbon materials for organic transformations

作　　者：李庆林 宋涛 杨勇 LI Qinglin;SONG Tao;YANG Yong(Qingdao Institute of Bioenergy and Bioprocess Technology,Chinese Academy of Sciences,Qingdao 266101,Shandong,China;University of Chinese Academy of Sciences,Beijing 100049,China;Shandong Energy Institute,Qingdao 266101,Shandong,China;Qingdao New Energy Shandong Laboratory,Qingdao 266101,Shandong,China)

机构地区：[1]中国科学院青岛生物能源与过程研究所,山东青岛266101 [2]中国科学院大学,北京100049 [3]山东能源研究院,山东青岛266101 [4]青岛新能源山东省实验室,山东青岛266101

出　　处：《化工进展》2021年第4期1966-1982,共17页Chemical Industry and Engineering Progress

基　　金：国家自然科学基金(22002178,22078350);山东省重点研发计划(2019GGX102075);英国皇家学会“牛顿高级学者”基金(NAF\R2\180695);山东省自然科学基金(ZR2020KB016)。

摘　　要：近年来,生物质因具有富碳可再生、储量丰富、环境友好、价格低廉等特点被作为原料广泛应用于制备生物质炭基材料。本文综述了以生物质为原料衍生炭基材料作为催化剂在有机转化反应中的相关研究进展,重点介绍了杂原子掺杂、金属杂化策略所制备炭基催化材料在液相催化加氢、氧化、偶联等有机转化反应中的催化性能,进而阐明了炭基催化剂与催化活性之间的构效关系。最后,本文总结了生物质炭基催化剂在有机催化反应中的优势,指出了目前生物质衍生炭基催化剂材料合成和有机转化研究领域面临的挑战,并对此领域的未来发展趋势进行了分析与展望。Recently,biomass has been intensively employed as an ideal carbon raw material to prepare carbon materials due to its rich carbon,natural abundance and renewability,environmental friendliness,and low-cost.This review summarizes the recent progress in design and preparation of carbon materials derived from various biomass feedstocks and in their application as catalysts for organic transformations.The focus was placed on those carbon catalysts prepared by heteroatoms-doping and metal-hybridization strategies and their applications in liquid-phase catalytic hydrogenation,oxidation,and coupling reactions.Meanwhile,the correlation between catalyst's structure and catalytic performance was elucidated accordingly.Lastly,the merits of biomass-based carbon catalysts in organic synthesis were summarized,and the current challenging and future perspectives for the design and preparation of biomass-based catalysts and their applications in organic transformation are provided.

关 键 词：生物质炭基材料 杂原子掺杂 金属纳米杂化结构催化剂 加氢反应 氧化反应 偶联反应 

分 类 号：O613.71[理学—无机化学] TQ21[理学—化学]