质子交换膜燃料电池催化剂纳米铂材料研究进展  

Research Progress on Pt-based Nanomaterials for ORR Electrocatalysts of PEMFC

作　　者：王志达 甘源 闫常峰[1] 刘光华 WANG Zhi-da;GAN Yuan;YAN Chang-feng;LIU Guang-hua(CAS Key Lab of Renewable Energy,Guangzhou Institute of Energy Conversion,Guangdong Key Lab of New and Renewable Energy Research and Development,Guangzhou 510640,China;Baida New Energy Company,Dongguan 523808,Guangdong,China)

机构地区：[1]中国科学院广州能源研究所中国科学院可再生能源重点实验室广东省新能源和可再生能源研究开发与应用重点实验室,广州510640 [2]百大新能源股份有限公司,广东东莞523808

出　　处：《贵金属》2020年第4期72-80,共9页Precious Metals

基　　金：国家自然科学基金项目(51576201);广东省自然科学基金研究团队项目(2015A030312007);东莞市引进创新科研团队项目(201460710200034);中国科学院可再生能源重点实验室基金项目(Y807j41001);STS区域重点项目(KFJ-STS-QYZD-2021-02-003)。

摘　　要：提高活性、降低贵金属担载量是质子交换膜燃料电池(PEMFC)催化剂的重点研究内容,纳米铂材料是提高阴极氧还原反应(ORR)活性的核心研究方向之一。基于对104篇文献的分析,综述了纳米铂颗粒的粒径、晶面和形貌对催化剂的活性和寿命的影响,以及纳米铂合金的成分和核-壳结构等因素对催化性能的影响。分析现有方法技术的优点和不足,提出催化剂有序化结构和优化ORR反应过程的研究方向。Improving the activity and reducing the amount of supported precious metals play an important role in the research of electrocatalysts for proton exchange membrane fuel cells(PEMFCs).Platinum(Pt)based nanomaterials are one of the key parts of enhancing the activity of the cathode catalysts on oxygen reduction reaction(ORR).Based on the analysis of 104 published papers,the influences of particle size,crystal facets and morphologies of the Pt-based nanoparticles(NPs)on the activity and stability of catalysts,as well as the alloy compositions and the core-shell structure on the catalytic performance,are discussed.By analyzing the advantages and shortcomings of the existing methods and technologies,and the research directions of designing catalysts with ordered nanostructure and optimizing the ORR process are proposed.

关 键 词：质子交换膜燃料电池 阴极催化剂 氧还原反应 纳米铂 活性 寿命 

分 类 号：TM911.4[电气工程—电力电子与电力传动] O643.3[理学—物理化学]