金属卟啉催化的三组分反应研究进展  

Progress on the Three-Component Reactions Catalyzed by Metalloporphyrins

作　　者：梅应轩 邹怀波[2] MEI Ying-xuan;ZOU Huai-bo(Department of Basic Medicine,Yichun Vocational Technical College,Yichun 336000,China;Key Laboratory of Jiangxi University for Applied Chemistry and Chemical Biology,Yichun University,Yichun 336000,China)

机构地区：[1]宜春职业技术学院医学基础部,江西宜春336000 [2]宜春学院江西省高校应用化学与化学生物学重点实验室,江西宜春336000

出　　处：《宜春学院学报》2021年第3期42-45,79,共5页Journal of Yichun University

基　　金：江西省教育厅科技计划项目(项目编号:GJJ151030,GJJ171341,GJJ180841)。

摘　　要：金属卟啉配合物,是一类具有重要应用价值的催化剂,在氧化、不对称合成、烯烃化、C-H键插入等反应中有着良好的应用。本文综述了金属卟啉配合物在三组分反应中的催化应用,重点归纳评述了它们在合成吡咯烷、吡咯啉、三氮唑、异噁唑、氮杂环丙烷等重要有机分子方面的催化活性,分析了目前金属卟啉配合物在这方面存在的问题并展望了其发展的方向。Metalloporphyrin is an important and valuable catalyst,which can be used in oxidation,asymmetrical synthesis,olefination and C-H bond insertion,etc.In this paper,the recent progress about catalytic application of metalloporphyrin in three-component reactions has been reviewed,with an emphasis on the preparation of pyrrolidines,pyrrolines,triazolidine and so on.The problems of metalloporphyrins in catalysis and several directions have also been addressed.

关 键 词：卟啉 金属配合物 催化 三组分反应 

分 类 号：O621.3[理学—有机化学]