Long-lasting photoluminescence quantum yield of cesium lead halide perovskite-type quantum dots  

作　　者：Yonghyun Kim Huiwen Liu Yi Liu Boa Jin Hao Zhang Wenjing Tian Chan Im 

机构地区：[1]Department of Chemistry,Konkuk University,Seoul 05029,Korea [2]State Key Laboratory of Supramolecular Structure and Materials,College of Chemistry,Jilin University,Changchun 130012,China

出　　处：《Frontiers of Chemical Science and Engineering》2021年第1期187-197,共11页化学科学与工程前沿（英文版）

基　　金：This work was supported by the research program of Konkuk University in 2018.

摘　　要：Cesium lead halide perovskite(CsPbX_(3),X=Cl,Br,I)quantum dots(QDs)and their partly Mn^(2+)-substituted QDs(CsPb1–xMnxX3)attract considerable attention owing to their unique photoluminescence(PL)efficiencies.The two types of QDs,having different PL decay dynamics,needed to be further investigated in a form of aggregates to understand their solid-state-induced exciton dynamics in conjunction with their behaviors upon degradation to achieve practical applications of those promising QDs.However,thus far,these QDs have not been sufficiently investigated to obtain deep insights related to the long-term stability of their PL properties as aggregated solid-states.Therefore,in this study,we comparatively examined CsPbX_(3)-and CsPb1–xMnxX_(3)-type QDs stocked for>50 d under dark ambient conditions by using excitation wavelength-dependent PL quantum yield and time-resolved PL spectroscopy.These investigations were performed with powder samples in addition to solutions to determine the influence of the inter-QD interaction of the aged QD aggregates on their radiative decays.It turns out that the Mn^(2+)-substituted QDs exhibited long-lasting PL quantum efficiencies,while the unsubstituted CsPbX_(3)-type QDs exhibited a drastic reduction of their PL efficiencies.And the obtained PL traces were clearly sensitive to the sample status.This is discussed with the possible interaction depending on the size and distance of the QD aggregates.

关 键 词：quantum dots cesium lead halide perovskite time-resolved photoluminescence PL quantum yield QD aggregates 

分 类 号：O62[理学—有机化学]