A Fe(Ⅱ) Coordination Polymer Based on 1,10-Phenanthroline Derivative and Oxalic Acid:Synthesis,Structure,and Properties  

作　　者：LI Xiu-Ying GAO Lin CHE Guang-Bo YAN Yong-Sheng LI Chun-Xiang 李秀颖;高林;车广波;闫永胜;李春香(School of Chemistry and Chemical Engineering,Jiangsu University,Zhenjiang 212013,China;College of Chemistry,Jilin Normal University,Siping 136000,China;College of Environmental Engineering,Jilin Normal University,Siping 136000,China)

机构地区：[1]School of Chemistry and Chemical Engineering,Jiangsu University,Zhenjiang 212013,China [2]College of Chemistry,Jilin Normal University,Siping 136000,China [3]College of Environmental Engineering,Jilin Normal University,Siping 136000,China

出　　处：《Chinese Journal of Structural Chemistry》2021年第3期317-323,272,共8页结构化学（英文）

基　　金：supported by the National Natural Science Foundation of China(No.21576112);the Project of Department of Science&Technology of Jilin Province(No.20180623042TC);Natural Scienceof Jilin Province(No.20170520143JH);the China Postdoctoral Science Foundation(No.2017M611732);the Science and Technology Research Projects of the Education Department of Jilin Province(No.JJKH20180791KJ);the Science and Technology Development Plan of Siping City(2017056)。

摘　　要：A Fe-based coordination polymer,[Fe(C_(2)O_4)_(0.5)(4-NCP)]_(n)·2nH_(2)O (1,4-HNCP=2-(4-carboxyphenyl)-1H-imidazo(4,5-f)-(1,10)phenanthroline,H_(2)C_(2)O_(4)=oxalic acid),was hydrothermally synthesized and characterized by infrared spectrum,elemental analysis,single-crystal X-ray diffraction,power X-ray diffraction,and UV-vis absorption spectrum.Structural analyses reveal that polymer 1 possesses a (4,4)-connected 2D network.In addition,1 shows photocatalytic activity toward the degradation of rhodamine B (RhB) in the presence of H_(2)O_(2) under visible light illumination.

关 键 词：Fe-based coordination polymer hydrothermal synthesis crystal structure photocatalytic activity 

分 类 号：X703[环境科学与工程—环境工程] O643.36[理学—物理化学] O644.1[理学—化学]