杭州老虎洞南宋官窑的制釉技术研究  

Study on the Glaze Producing Technology of Guan Kiln from the Laohudong of the Southern Song Dynasty in Hangzhou

作　　者：李合[1] 侯佳钰[1] 丁银忠[1] 唐俊杰[2] 王光尧[1] LI He;HOU Jiayu;DING Yinzhong;TANG Junjie;WANG Guangyao(The Palace Museum,Beijing 100009,China;Archeological Institute of Hangzhou,Hangzhou 310002,China)

机构地区：[1]故宫博物院,北京100009 [2]杭州市文物考古研究所,杭州310002

出　　处：《中国陶瓷》2021年第4期56-61,共6页China Ceramics

基　　金：国家重点研发计划资助(2019YFC1520202);江西协同中心课题(JXYY1901);国家自然科学基金(51402054、51702054)。

摘　　要：为进一步揭示杭州老虎洞窑宋代地层出土官窑青瓷的制釉技术特征和时代发展规律,本文对老虎洞窑宋代地层出土官窑青瓷标本的釉以及杭州当地草木灰、石灰石样品进行了锶同位素比值(^(87)Sr/^(86)Sr)、主次量元素和微量元素含量测定。结果表明:1)老虎洞窑宋代地层出土官窑青瓷釉料为三元配方,即南宋时期老虎洞窑官窑青瓷釉料是以高硅质原料配以适量的草木灰、石灰石烧制而成;而高硅质原料、草木灰和石灰石三者之间的配比,关系导致了南宋早、晚期官窑青瓷釉料组成发生改变,即由钙釉向钙碱釉转变。2)南宋早期官窑青瓷和晚期官窑青瓷釉料的锶同位素比值(^(87)Sr/^(86)Sr)比值不同,表明锶同位素比值方法可用于南宋官窑青瓷的断代研究,值得今后进一步研究。In order to study the glaze producing technology of Guan ware shards from Laohudong kiln site,the Sr isotope ratios(^(87)Sr/^(86)Sr),major and trace elements of glaze of Guan ware shards,porcelain stone and limestone samples unearthed from Laohudong of Song Dynasty were determined by TIMS,EDXRF and ICP-MS methods.The results showed that:1)According to the data of Sr isotope ratios and chemical compositions,it could be speculated that three raw materials,siliceous material,limestone and wood ash may be used to make Guan ware glaze.2)The Sr isotope ratio values of Guan ware glaze become larger along with CaO content decreasing and K_(2)O increasing.This work shows that.the Sr isotope ratio method could be useful for study on the dating of Guan ware,which is worthy to be studied in the future.

关 键 词：老虎洞窑 南宋官窑 锶同位素 制釉技术 

分 类 号：TQ174.43[化学工程—陶瓷工业]