Nanostructured amorphous Fe_(29)Co_(27)Ni_(23)Si_(9)B_(12) high-entropy-alloy:an efficient electrocatalyst for oxygen evolution reaction  

作　　者：Hongyan Wang Ran Wei Xiumin Li Xuli Ma Xiaogang Hao Guoqing Guan 

机构地区：[1]School of Materials Science and Engineering,Zhengzhou University,Zhengzhou 450001,China [2]Department of Environmental Science and Engineering,Taiyuan University of Technology.Taiyuan 030024,China [3]Department of Chemical Engineering,Taiyuan University of Technology,Taiyuan 030024,China [4]Energy Con version Engineering Laboratory,Institute of Regional Innovation,Hirosaki University,2-1-3 Matsubara,Aomori 030-0813,Japan

出　　处：《Journal of Materials Science & Technology》2021年第9期191-198,共8页材料科学技术（英文版）

基　　金：The financial supports from the key research&development and promotion of special project of Henan province (science&technology)(Grant No.192102210006);the Scientific Research Foundation of Zhengzhou University (32210862,32211241)。

摘　　要：Proximal configu ration of dissimilar metal atoms in amorphous high-entropy-alloys(HEAs) always re sult in interatomic d-band ligand effect,dense defect distribution,coordinatively unsaturated sites,high potential energy,and loose atom bonding.Herein,nanostructured amorphous Fe_(29)Co_(27)Ni_(23)Si_(9)B_(12) HEA ribbon is fabricated via a melt spinning method combined with electrochemical corrosion etching process,which is applied as the potential oxygen evolution reaction electrocatalyst.It is found that there are micro/nano pits on the surface of etched amorphous Fe_(29)Co_(27)Ni_(23)Si_(9)B_(12) ribbons.Various elements of HEAs bond with each other to form a highly disordered configu ration,which could result in an optimized bonding energy and enhanced intrinsic catalytic activity.The electrocatalysis activity measurements indicate that the amorphous HEA endows a much higher activity than the crystalline one,which is further improved by the electrochemical etching treatment.Especially,the HEA ribbon etched for 3 h requires a low overpotential of 230 mV to afford 10 mA cm^(-2) current density.In addition,density functional theory calculations demonstrate that the amorphous structure can weaken the interaction between the surface of Fe_(29)Co_(27)Ni_(23)Si_(9)B_(12) alloy and the intermediates,leading to an optimized adsorption Gibbs free energy.

关 键 词：Water splitting High-entropy-alloys Oxygen evolution reaction ELECTRO-CATALYST 

分 类 号：TQ116.2[化学工程—无机化工] TQ426