柱状石墨烯膜反渗透滤盐特性及机理  

Reverse osmotic characteristics and mechanism of pillared graphene membranes for water desalination

作　　者：张泽程 刘珍[2] 王孟妮 张福建 张忠强[1,3] Zhang Ze-Cheng;Liu Zhen;Wang Meng-Ni;Zhang Fu-Jian;Zhang Zhong-Qiang(Institute of Intelligent Flexible Mechatronics,Jiangsu University,Zhenjiang 212013,China;School of Naval Architecture and Ocean Engineering,Jiangsu University of Science and Technology,Zhenjiang 212003,China;Jiangsu Collaborative Innovation Center of Photovoltaic Science and Engineering,Changzhou University,Changzhou 213164,China)

机构地区：[1]江苏大学智能柔性机械电子研究院,镇江212013 [2]江苏科技大学船舶与海洋工程学院,镇江212003 [3]常州大学,江苏省光伏科学与工程协同创新中心,常州213164

出　　处：《物理学报》2021年第9期339-348,共10页Acta Physica Sinica

基　　金：国家自然科学基金(批准号:11872192)资助的课题。

摘　　要：柱状石墨烯在能源气体的存储运输和气体净化分离等方面备受关注,但其在海水淡化方面受到了大面积制备的限制,其反渗透特性和机理尚未明晰.本文运用分子动力学方法研究了不同压强、温度和膜的剪切运动对柱状石墨烯膜反渗透滤盐特性的影响规律.结果表明:压强较大时,水通量随着压强的增加而线性增加;温度的升高能提升水分子渗透率,但对离子截留率的影响不大;反渗透膜的剪切运动虽然会阻碍水分子的渗透,但相应地可以提高离子截留率.对氢键和离子水合结构的分析表明,反渗透膜的剪切运动可以提高氢键和离子水合壳的稳定性,但温度的升高会产生相反的效果.本文结果有助于深入理解柱状石墨烯膜在不同条件下的脱盐性能,进一步验证了柱状石墨烯膜在海水淡化领域的巨大应用潜力.Because of the high water flux and excellent ion rejection,the pores graphene is considered as a promising candidate material for fabricating the membranes in reverse osmosis(RO)process.Unfortunately,water molecules cannot pass through the perfect graphene,and how to effectively create a large number of nanopores with controllable size remains a challenge,which seriously prevents the practical application and development of graphene membrane for desalination.Recently,the emergence of pillared graphene(PGN)might open a new way for designing the graphene-based membranes,which can compensate for the deficiency of porous graphene membrane.The PGN has been extensively studied in gas storage and separation,and its RO characteristics and mechanism still remain unclear because the limitation of large area preparation in desalination.In this paper,the RO process of seawater through PGN membranes is investigated by molecular dynamics simulations,and the influences of the pressure within feed solution,temperature and the shearing of membrane on the desalination properties are considered.It is found that the water flux increases linearly with the pressure within feed solution increasing,and the PGN membrane with nanopore diameter of 0.8 nm can conduct water molecules but completely rejects high-concentration ions.As the diameter of nanopores increases to 1.2 nm,the rise of temperature can increase the permeability of water molecules,whereas the salt rejection is not appreciably sensitive to the temperature.Particularly,the shearing membrane can improve the salt rejection and hinder the water molecules from permeating at the same time.The designed PGN membrane exhibits excellent performance of water purification,and the ultrahigh water flux obtained in this work reaches 56.15 L·cm–2·day–1·MPa–1 with a salt rejection of 88.9%.Subsequently,the hydrogen bond dynamics is calculated in order to explain the variation of water permeability under different conditions.The result shows that the rise of temperature reduces the

关 键 词：柱状石墨烯 反渗透 分子动力学 氢键 水合离子 

分 类 号：TQ051.893[化学工程]