金属有机框架(MOFs)材料在锂离子电池及锂金属电池电解液中的应用  

Applications of Metal-organic Frameworks(MOFs) Materials in Lithium-ion Battery/Lithium-metal Battery Electrolytes

作　　者：常智 乔羽 杨慧军 邓瀚 朱星宇 何平[1] 周豪慎[1,2,3] Zhi Chang;Yu Qiao;Huijun Yang;Han Deng;Xingyu Zhu;Ping He;Haoshen Zhou(Center of Energy Storage Materials&Technology,College of Engineering and Applied Sciences,National Laboratory of Solid State Microstructures,and Collaborative Innovation Center of Advanced Microstructures,Nanjing University,Nanjing 210093,China;Energy Technology Research Institute,National Institute of Advanced Industrial Science and Technology(AIST),Tsukuba 305-8568,Japan;Graduate School of System and Information Engineering,University of Tsukuba,1-1-1,Tennoudai,Tsukuba 305-8573,Japan)

机构地区：[1]南京大学储能材料与技术中心,现代工程与应用科学学院,固体微结构国家重点实验室,人工微结构科学与技术协同创新中心,中国南京210093 [2]产业技术综合研究所(AIST)能源技术研究所,日本筑波305-8568 [3]日本国立筑波大学(University of Tsukuba)系统与信息工程研究生院,日本筑波305-8573

出　　处：《化学学报》2021年第2期139-145,共7页Acta Chimica Sinica

基　　金：国家重点研究发展计划(No.2016YFB0100203);国家自然科学基金(Nos.21673166,21633003,u1801252)资助。

摘　　要：总结了金属有机框架(MOFs)材料在锂离子电池电解液中的研究进展.通过归纳锂离子电池长期存在的一些缺陷,随后将MOFs材料作为离子筛、人造负极保护层、准固态电解质以及用来调节电解液构型,使得锂离子电池的性能得到显著提升.最后,基于MOFs材料本身的特性,还对MOFs材料在电化学储能领域中的后续应用进行了合理地前瞻性展望.This perspective summarizes the research progress of metal-organic frameworks(MOFs) materials used in lithium-ion battery/lithium-metal electrolytes. By summarizing several long-standing defects of lithium-ion batteries/lithiummetal batteries, MOFs materials are subsequently used as ion sieves, artificial electrode protective layers, quasi-solid electrolytes and used to adjust electrolytes’ configuration, the performance of batteries has been significantly improved. Finally, based on the characteristics of MOFs materials themselves, this perspective also makes a reasonable forward-looking outlook on the subsequent applications of MOFs materials in the field of electrochemical energy storage.

关 键 词：金属有机框架(MOFs) 锂离子电池 离子筛 负极保护 准固态电解质 

分 类 号：TM912[电气工程—电力电子与电力传动] O641.4[理学—物理化学]