The production of biobased diamines from renewable carbon sources: Current advances and perspectives  

作　　者：Xin Wang Siyuan Gao Jing Wang Sheng Xu Hui Li Kequan Chen Pingkai Ouyang 

机构地区：[1]State Key Laboratory of Materials-Oriented Chemical Engineering,College of Biotechnology and Pharmaceutical Engineering,Nanjing Tech University,Nanjing 211816,Jiangsu,China [2]Zhejiang Zhongshan Chemical Industry Group Co.Ltd,Huzhou 313100,Chin

出　　处：《Chinese Journal of Chemical Engineering》2021年第2期4-13,共10页中国化学工程学报（英文版）

基　　金：This work was supported by the National Key Research and Development Program of China(Grant No.2018YFA0901500);National Nature Science Foundation of China(Grant No.21606127,Grant No.21706126);Jiangsu synergetic innovation center for advanced bio-manufacture(Grant No.XTB1802,Grant No.XTE1844).

摘　　要：Bio-based diamines are considered to be a promising alternative to traditional fossil-fuel-based diamines,the important platform chemical for the synthesis of polymer materials.In this review,the current status of the art of the synthesis of aliphatic and aromatic diamines from renewable biomass are considered.In the case of aliphatic diamines,we describe strategies for biologically producing diamines with different carbon numbers including 1,3-diaminopropane,1,4-butanediamine,1,5-pentanediamine,1,6-diaminohexane,1,8-diaminooctane,1,10-diaminodecane,and 1,12-diaminododecane.In addition,aromatic diamines produced from various kinds of renewable biomass,including lignin,cashew nut shell,and terpenoids,are reviewed here.Furthermore,the application of typical diamines in synthesis of polyurethane and polyamide are also reviewed.

关 键 词：Aliphatic diamines Aromatic diamines POLYAMIDE POLYURETHANE 

分 类 号：TQ226.31[化学工程—有机化工] TQ314