Ionic liquids for CO_(2) electrochemical reduction  

作　　者：Fangfang Li Francesca Mocci Xiangping Zhang Xiaoyan Ji Aatto Laaksonen 

机构地区：[1]Energy Engineering,Division of Energy Science,LuleåUniversity of Technology,Luleå97187,Sweden [2]Department of Chemical and Geological Sciences,University of Cagliari,Monserrato 09042,Italy [3]CAS Key Laboratory of Green Process and Engineering,Beijing Key Laboratory of Ionic Liquids Clean Process,State Key Laboratory of Multiphase Complex Systems,Institute of Process Engineering,Chinese Academy of Sciences,Beijing 100190,China [4]Division of Physical Chemistry,Department of Materials and Environmental Chemistry,Arrhenius Laboratory,Stockholm University,Stockholm 10691,Sweden [5]Center of Advanced Research in Bionanocojugates and Biopolymers,“Petru Poni”Institute of Macromolecular Chemistry,Iasi 700469,Romania [6]State Key Laboratory of Materials-Oriented and Chemical Engineering,Nanjing Tech University,Nanjing 211816,China

出　　处：《Chinese Journal of Chemical Engineering》2021年第3期75-93,共19页中国化学工程学报（英文版）

基　　金：F.Li and X.Ji thank the financial support from the Swedish Energy Agency(P47500-1);A.Laaksonen acknowledges the Swedish Research Council for financial support(2019-03865);partial support from a grant from Ministry of Research and Innovation of Romania(CNCS-UEFISCDI,project number PN-IIIP4-ID-PCCF-2016-0050,within PNCDI III);F.Mocci thanks the Fondazione di Sardegna,Project:“Precious metal-free complexes for catalytic CO2 reduction”(CUP:F71I17000170002)for the financial support.

摘　　要：Electrochemical reduction of CO_(2) is a novel research field towards a CO_(2)-neutral global economy and combating fast accelerating and disastrous climate changes while finding new solutions to store renewable energy in value-added chemicals and fuels.Ionic liquids(ILs),as medium and catalysts(or supporting part of catalysts)have been given wide attention in the electrochemical CO_(2) reduction reaction(CO_(2) RR)due to their unique advantages in lowering overpotential and improving the product selectivity,as well as their designable and tunable properties.In this review,we have summarized the recent progress of CO_(2) electro-reduction in IL-based electrolytes to produce higher-value chemicals.We then have highlighted the unique enhancing effect of ILs on CO_(2) RR as templates,precursors,and surface functional moieties of electrocatalytic materials.Finally,computational chemistry tools utilized to understand how the ILs facilitate the CO_(2) RR or to propose the reaction mechanisms,generated intermediates and products have been discussed.

关 键 词：Carbon dioxide Ionic liquids ELECTRO-REDUCTION ELECTROLYTE Electrocatalytic material Computer simulation 

分 类 号：TQ426[化学工程] O645.1[理学—物理化学] X701[理学—化学]