Prediction and verification of heat capacities for pure ionic liquids  

作　　者：Zhengxing Dai Yifeng Chen Chang Liu Xiaohua Lu Yanrong Liu Xiaoyan Ji 

机构地区：[1]State Key Laboratory of Material-Oriented Chemical Engineering,Nanjing Tech University,Nanjing 211816,China [2]Energy Engineering,Division of Energy Science,LuleåUniversity of Technology,Luleå,Sweden [3]Swerim AB,Box 812,SE-97125 Luleå,Sweden

出　　处：《Chinese Journal of Chemical Engineering》2021年第3期169-176,共8页中国化学工程学报（英文版）

基　　金：financially supported by the Joint Research Fund for Overseas Chinese Scholars and Scholars in Hong Kong and Macao Young Scholars(No.21729601);the National Natural Science Foundation of China(No.21838004);financial support from Carl Tryggers Stiftelse foundation(No.18:175);financial support from Swedish Energy Agency(P50830-1);financial support from National Natural Science Foundation of China(No.21878143)。

摘　　要：The heat capacity of ionic liquids is an important physical property,and experimental measuring is usually used as a common method to obtain them.Owing to the huge number of ionic liquids that can be potentially synthesized,it is desirable to acquire theoretical predictions.In this work,the Conductor-like Screening Model for Real Solvents(COSMO-RS)was used to predict the heat capacity of pure ionic liquids,and an intensive literature survey was conducted for providing a database to verify the prediction of COSMO-RS.The survey shows that the heat capacity is available for 117 ionic liquids at temperatures ranging 77.66-520 K since 2004,and the 4025 data points in total with the values from 76.37 to 1484 J·mol^(-1)·K^(-1) have been reported.The prediction of heat capacity with COSMO-RS can only be conducted at two temperatures(298 and 323 K).The comparison with the experimental data proves the prediction reliability of COSMO-RS,and the average relative deviation(ARD)is 8.54%.Based on the predictions at two temperatures,a linear equation was obtained for each ionic liquid,and the heat capacities at other temperatures were then estimated via interpolation and extrapolation.The acquired heat capacities at other temperatures were then compared with the experimental data,and the ARD is only 9.50%.This evidences that the heat capacity of a pure ionic liquid follows a linear equation within the temperature range of study,and COSMO-RS can be used to predict the heat capacity of ionic liquids reliably.

关 键 词：Ionic liquids Heat capacity COSMO-RS 

分 类 号：O645.1[理学—物理化学]