铜镉渣酸浸液旋流电积提铜对比分析  

Comparative analysis of copper extraction from leachate of Cu-Cd residues by cyclone electrowinning

作　　者：顾利坤 徐洪傲 李博[2] 魏永刚[2] GU Likun;XU Hong’ao;LI Bo;WEI Yonggang(Huize Smelting Branch,Yunnan Chihong Zinc Germanium Co.,Ltd.,Huize 654200,Yunnan,China;State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization,Kunming University of Science and Technology,Kunming 650093,Yunnan,China)

机构地区：[1]云南驰宏锌锗股份有限公司会泽冶炼分公司,云南会泽654200 [2]昆明理工大学省部共建复杂有色金属资源清洁利用国家重点实验室,云南昆明650093

出　　处：《化工进展》2021年第5期2900-2908,共9页Chemical Industry and Engineering Progress

基　　金：国家自然科学基金(51764035);云南省自然科学基金(2018FB089)。

摘　　要：针对湿法炼锌副产物铜镉渣氧化酸浸液成分特点,采用旋流电积工艺回收其中的金属铜。研究了不同旋流电积工艺对电积过程中相关技术参数及杂质离子迁移规律的影响,并对不同电积工艺的优缺点进行了对比分析。结果表明:一段旋流电积可使溶液中铜离子浓度从44.14g/L降低到1.42g/L,而分段旋流电积可使溶液中终点铜离子浓度从1.42g/L继续降低至0.5g/L以下,溶液中铜离子在阴极上的电沉积率可从96.78%提高到99.20%,阴极电流效率可从90.52%提高到98.49%。当溶液中铜离子浓度降低到10g/L左右及以下时,杂质离子在阴极与铜发生共沉积现象逐渐明显,分段旋流电积得到的阴极铜产品光泽度及形貌质量较一段电积更好。与一段旋流电积工艺相比,分段旋流电积工艺具有电流效率高、能耗低、产品质量好等优点。A process for copper extraction using cyclone electrowinning technology was carried out,based on the composition characteristics of the oxidation acid leaching solution of copper-cadmium residues.The effects of different cyclone electrowinning processes on the relevant technical parameters and impurity ions migration behavior in the electrowinning process were investigated.The advantages and disadvantages of different electrowinning processes were analyzed.The results show that the concentration of copper ion in the solution can be reduced from 44.14g/L to 1.42g/L by one-stage cyclone electrowinning.While,the end-point copper ion concentration in the solution can be reduced from 1.42g/L to less than 0.5g/L by segmented cyclone electrowinning.Additionally,the electrodeposition efficiency of copper ions on the cathode can be increased from 96.78%to 99.20%with the current efficiency increased from 90.52%to 98.49%.When the concentration of copper ion was reduced to 10g/L or less,the codeposition of impurity ions and copper in the cathode is obvious.The gloss and morphology quality of the cathode copper products obtained by the segmented cyclone electrowinning process are better.Compared with one-stage cyclone electrowinning,the segmented cyclone electrowinning process has the advantages of high current efficiency,low energy consumption,and better product quality,etc.

关 键 词：铜镉渣酸浸液 旋流电积 分段电积 电流效率 金属铜 

分 类 号：TF8[冶金工程—有色金属冶金]