烷氧基桥连双卟啉锌(Ⅱ)配合物的合成与光谱性质  

Synthesis and Spectral Properties of Alkoxy Bridged Bisporphyrin Zinc(Ⅱ) Complex

作　　者：林尊贤 练萍[1,2] 周丹荔 罗国添[1,2] LIN Zunxian;LIAN Ping;ZHOU Danli;LUO Guotian(School of Chemistry and Chemical Engineering,Gannan Normal University,Ganzhou 341000,China;Key Laboratory of Jiangxi Organo-Pharmaceutical Chemistry,Gannan Normal University,Ganzhou 341000,China)

机构地区：[1]赣南师范大学化学化工学院,江西赣州341000 [2]赣南师范大学江西省有机药物化学重点实验室,江西赣州341000

出　　处：《赣南师范大学学报》2021年第3期65-68,共4页Journal of Gannan Normal University

基　　金：国家自然科学基金(20761001,21161001);江西省教育厅科技计划(GJJ201423)。

摘　　要：以吡咯、苯甲醛、对羟基苯甲醛、1,8-二溴辛烷等为原料合成一种新型烷氧氨基桥连双卟啉锌(Ⅱ)配合物,并用紫外-可见光谱、红外光谱、核磁共振氢谱、质谱等手段对其进行结构表征.荧光光谱研究结果表明:烷氧基桥连双卟啉及其锌(Ⅱ)配合物分别在652 nm和598 nm、642 nm处有较强的荧光发射,位于可见光的红光区,有望成为一类具有实际应用前景的新型光敏剂.A new alkoxy bridged bisporphyrin and its zinc(Ⅱ) complex were synthesized from benzaldehyde,pyrrole,p-hydroxybenzaldehyde and 1,8-bisbromooctane.Their structures were characterized by UV-vis,IR,NMR and MS.And fluorescence spectrum were researched.The results show that the alkoxy bridged porphyrin and its zinc(Ⅱ) complex have strong fluorescence emission at 652 nm and 598 nm,642 nm,respectively,and located at the red light district,in that point,they expected to become a kind of new photosensitizer can be used.

关 键 词：双卟啉 锌(Ⅱ)配合物 合成 光谱性质 

分 类 号：O629.9[理学—有机化学]