乙烯-丙烯酸(酯)类共聚物合成的新进展  

New research progress of copolymerization of ethylene-acrylic acid(acrylate)

作　　者：姚圣泽 朱煦 王以元 施云海[1] Yao Shengze;Zhu Xu;Wang Yiyuan;Shi Yunhai(Research Centre of Chemical Engineering,East China University of Science and Technology,Shanghai 200237,China;Shanghai M.Land Chemical Co.,Ltd.,Shanghai 200237,China)

机构地区：[1]华东理工大学化学工程研究所,上海200237 [2]上海摩田化学有限公司,上海200237

出　　处：《中国胶粘剂》2021年第4期69-75,共7页China Adhesives

摘　　要：概述了不同类型的乙烯-丙烯酸(酯)共聚物及与此相关产品的性质与用途,并就乙烯-丙烯酸(酯)类共聚物的合成从高温超高压反应逐渐往低温低压方向的进展进行了阐述。还对用于该共聚的不同后过渡金属催化剂配体及其催化性能,如α-二亚胺(N^N)、膦磺酸盐(P^O)、双膦一氧化物(BPMO)、膦酚(PhOP)等的钯或镍新配体体系进行了论述。最后对乙烯-丙烯酸(酯)类共聚物的发展进行了展望。The properties and application of different types of ethylene-acrylic acid(acrylate)copolymers and related products were summarized. The progress in the synthesis of ethylene-acrylic acid(acrylate)copolymers from high temperature and high pressure reaction to low temperature and low pressure reaction was reviewed. In addition,different late transition metal catalyst ligands used in the copolymerization and their catalytic properties were also discussed,such as new palladium or nickel ligand systems with α-diimine(N^N),phosphine sulfonate(P^O),bisphosphine monoxide(BPMO)and phosphino-phenolate(PhOP). Finally,the development of ethylene-acrylic acid(acrylate)copolymers was prospected.

关 键 词：乙烯 丙烯酸(酯) 乙烯-丙烯酸酯类共聚物 共聚反应 后过渡金属催化剂 

分 类 号：TQ433[化学工程]