富氮稠环类氮氧化物的研究进展  

Research Progress of Nitrogen⁃rich Fused⁃ring N⁃oxides

作　　者：刘赛 石伟[1] 王毅[2] 张庆华[2] LIU Sai;SHI Wei;WANG Yi;ZHANG Qing-hua(College of Chemistry and Chemical Engineering,Southwest Petroleum University,Chengdu 610500,China;Institute of Chemical Materials,CAEP,Mianyang 621999,China)

机构地区：[1]西南石油大学化学化工学院,四川成都610500 [2]中国工程物理研究院化工材料研究所,四川绵阳621999

出　　处：《含能材料》2021年第6期567-578,I0010,共13页Chinese Journal of Energetic Materials

基　　金：国家自然科学基金资助(22075259,21875288)。

摘　　要：富氮稠环类氮氧化物由于其平面共轭的分子骨架结构和共价氮氧键官能团,通常具有密度高、爆轰性能优异及感度适中等优点,因此,这类化合物已逐渐成为含能材料领域的研究热点。本研究综述了近十年来合成的20种富氮稠环类氮氧化物的分子结构、合成方法及理化性能等,比较了富氮稠环分子氮氧化前后的主要理化性能参数,为其合成及性能研究提供一定的参考。Due to conjugated planar molecular structure and additional N‑oxide bonds,nitrogen‑rich fused‑ring N‑oxides usually exhibit the advantages of high density,good detonation performances and good sensitivity and they have gradually become a research hotspot of energy materials.This article reviewed molecular structure,synthesis method and physical and chemical properties of twenty nitrogen‑rich fused‑ring N‑oxides that were synthesized in the last decade.At the same time,this article com‑pared some main physical and chemical properties between nitrogen‑rich fused‑ring N‑oxides and their precursors.This review will provide some references for the synthesis and property investigation of new nitrogen‑rich fused‑ring N‑oxides.

关 键 词：氮氧化物 富氮稠环 含能材料 

分 类 号：TJ55[兵器科学与技术—军事化学与烟火技术] O64[理学—物理化学]