Recent advances in catalytic conversion of carbon dioxide to propiolic acids over coinage-metal-based catalysts  

作　　者：Tianyu Zhang Jiawei Zhong Zhilian Wu 

机构地区：[1]Department of Chemistry,Joint Institute for Advanced Materials,University of Tennessee,37996 Knoxville,United States [2]Department of Chemical and Biomolecular Engineering,National University of Singapore,4 Engineering Drive,117585 Singapore,Singapore [3]Ningbo Fengcheng Advanced Energy Materials Research Institute Co.,Ltd.,Ningbo 315500,China [4]College of Materials Science and Engineering,Shenzhen University,Shenzhen 518055,China

出　　处：《Journal of Energy Chemistry》2021年第8期572-580,I0012,共10页能源化学（英文版）

摘　　要：The conversion of inexpensive,available C1 feedstock of carbon dioxide(CO_(2))into value-added fine chemicals via homogeneous or heterogeneous catalysis has attracted great recent interest.Coinagemetal-based(Cu,Ag,and Au)catalysis has emerged as a synthetic strategy for a wide range of organic chemical reactions in past decades.In coinage-metal-catalyzed carboxylation,CO_(2)is adopted as a carboxylation reagent,while coinage-metal salts,complexes,and nanoparticles(NPs)serve as a Lewis acid catalyst to activate unsaturated chemicals,particularly alkynes.This mini-review focuses on the recent advances of coinage-metal-catalyzed carboxylation of terminal alkynes with CO_(2).Other respects,such as the role of bases,the influence of trace water,and solvent effects are also highlighted.

关 键 词：Carbon dioxide Terminal alkynes Propiolic acids CATALYSIS 

分 类 号：TQ225.123[化学工程—有机化工] TQ426