亲金作用驱动的环状超分子簇合物研究进展  

Research progress of macrocyclic supramolecular clusters driven by aurophilicity interaction

作　　者：蒋选丰 杨洁 JIANG Xuan-feng;YANG Jie(School of Materials Science and Engineering,Hubei University,Wuhan 430062,Hubei,China)

机构地区：[1]湖北大学材料科学与工程学院,湖北武汉430062

出　　处：《黄冈师范学院学报》2021年第3期64-71,共8页Journal of Huanggang Normal University

基　　金：国家自然科学基金面上项目(21971058);湖北省杰出青年基金项目(2020CFA085)。

摘　　要：多金属中心簇化合物因其具有新颖的分子结构、丰富的物理化学性质以及在光学材料、化学传感器和无机药物等方面的潜在应用而受到越来越多的关注。随着金属-金属成键作用在复杂体系中的广泛应用,含有多金属中心的超分子簇合物材料在可控合成方法、结构多样性和功能化等方面已经得到很大的发展,并且产生了大量具有特殊结构和性能的超分子簇合物聚集体材料。本文系统介绍了亲金作用驱动的多核超分子簇合物的自组装策略、几类典型大环超分子簇合物的可控合成实例和超分子簇合物材料的潜在应用,为系统研究多核金(I)超分子簇合物的精确合成、结构和性能优化提供参考。Polymetallic central cluster compounds have attracted more and more attention because of their novel molecular structures,rich physical and chemical properties and potential applications in optical materials,chemical sensors and inorganic drugs.With the wide application of metal-metal bonding interaction in complex systems,supramolecular cluster materials with polymetallic centers have been greatly developed in controllable synthesis methodology,structural diversity and functionalization.In recent years,a large number of novel supramolecular cluster aggregate materials with special structures and properties have been produced.This review systematically introduced the self-assembly strategy of polynuclear supramolecular clusters driven by aurophilicity interaction.Furthermore,several interesting examples of typical macrocyclic supramolecular clusters and their potential applications were also presented in this paper.The purpose of this study was to provide a reference for the systematic study of the precise synthesis,structure and performance optimization of polynuclear gold(I)supramolecular clusters.

关 键 词：金属-金属成键作用 可控自组装 超分子簇化合物 亲金作用 

分 类 号：O611.4[理学—无机化学]