Mannich反应机理及其改性工业化学品的研究进展  

Research progress in mechanism and modifying industrial chemicals of Mannich reaction

作　　者：刘启武 马建中 田振华 LIU Qiwu;MA Jianzhong;TIAN Zhenhua(College of Bioresources Chemical and Materials Engineering,Shaanxi University of Science&Technology,Xi'an 710021,CMna;Key Laboratory of Leather Cleaner Production,China National Light Industry,Xi'an 710021,China)

机构地区：[1]陕西科技大学轻工科学与工程学院,陕西西安710021 [2]中国轻工业皮革清洁生产重点实验室,陕西西安710021

出　　处：《中国皮革》2021年第5期26-32,共7页China Leather

基　　金：国家自然科学基金重点项目(21838007);国家自然科学基金(21706151)。

摘　　要：Mannich反应是一种常用的合成及改性聚合物的手段,其反应条件温和,易于控制,并且制备的聚合物性能稳定,常用于目标产物中间体的制备以及功能性聚合物的合成.系统综述了Mannich反应的发展历程;介绍了Mannich反应组分之间的相互作用、反应机理及其在工业方面的应用,如阻燃剂、絮凝剂、缓蚀剂方面的应用;重点阐述了Mannich反应在皮革交联剂方面的应用研究,归纳了Mannich反应在皮革交联剂方面所面临的问题,并展望了其发展趋势.Mannich reaction is a commonly used method to synthesize and modify polymers. Its reaction conditions are mild and easy to control, and the obtained polymers have stable properties. Therefore, it is often used in the preparation of the intermediates of target products and the synthesis of functional polymers. The development of Mannich reaction was reviewed systematically. Additionally, the interaction between components and mechanism of Mannich reaction, and its applications in industrial fields were introduced, such as flame retardant, flocculant, corrosion inhibitor, especially leather crosslinking agent. Furthermore, the problems of Mannich reaction in leather crosslinking agent were summarized, and its development trend was prospected.

关 键 词：MANNICH反应 多组分反应 反应机理 应用 皮革交联剂 

分 类 号：TQ31[化学工程—高聚物工业]