以硅藻土为原料制备铯吸附剂及其吸附性能初探  

Preparation of cesium adsorbent from diatomite and its adsorption properties

作　　者：董超超 邓小川[1,2] 王斌 樊发英 朱朝梁[1,2] 樊洁 卿彬菊[1,2] Dong Chaochao;Deng Xiaochuan;Wang Bin;Fan Faying;Zhu Chaoliang;Fan Jie;Qing Binju(Key Laboratory of Comprehensive and Highly Efficient Utilization of Salt Lake Resources,Qinghai Instituteof Salt Lakes,Chinese Academy of Sciences,Xining 810008,China;Qinghai Engineering and Technology Research Center of Comprehensive Utilization of Salt Lake Resources;University of ChineseAcademy of Sciences)

机构地区：[1]中国科学院青海盐湖研究所中国科学院盐湖资源综合高效利用重点实验室,青海西宁810008 [2]青海省盐湖资源综合利用工程技术中心 [3]中国科学院大学

出　　处：《无机盐工业》2021年第6期134-139,共6页Inorganic Chemicals Industry

基　　金：青海省科技厅应用基础研究项目(2017-Zj-726);中科院项目(IAGM-2019-A04和KFJ-HGZX-008)。

摘　　要：铯是一种极为重要的稀有碱金属资源,在光纤通信、催化、医疗以及能源等领域有着广泛的应用。中国青海、西藏等地的盐湖卤水中蕴藏着储量可观的铯资源有待开发,因此开展溶液中铯离子分离提取技术的研究意义重大。以无毒且价廉的硅藻土为硅源,以三嵌段聚合物P-123为模板剂,采用一步法合成了磷钼酸铵负载量为27%(质量分数)的磷钼酸铵/二氧化硅(AMP/SiO_(2))复合吸附材料用于吸附铯离子(Cs^(+))。通过扫描电镜(SEM)、X射线衍射(XRD)、傅里叶变换红外光谱仪(ICP-OES)等对合成的AMP/SiO_(2)进行了表征,并初步考察了AMP/SiO_(2)对水溶液中Cs~+的吸附性能。研究结果表明,AMP较为均匀地分散在介孔二氧化硅的结构和孔道中,并且该复合材料有较大的比表面积(451.2 m^(2)/g)和孔体积(0.95 cm^(3)/g)。此外,该吸附剂对Cs^(+)的吸附过程符合拟二级动力学模型和Freundlich等温吸附模型,Cs^(+)平衡吸附容量可达63.45 mg/g。Cesium is an extremely important rare alkali metal resource,which is widely used in the fields of optical fiber communication,catalysis,medical treatment and energy.There are considerable reserves of cesium in the salt lake brine in Qinghai,Tibet and other places to be developed.Therefore,it is of great significance to carry out research on the separation and extraction technology of cesium ions in solution.Non-toxic and inexpensive diatomite was used as the silicon source,triblock polymer P-123 was used as a template agent,and the one step synthesis method was used to synthesize AMP/SiO_(2) composite adsorbent with ammonium molybdophosphate(AMP)loading of 27%used to adsorb cesium ion(Cs+).The AMP/SiO_(2) was characterized by scanning electron microscope(SEM),X-ray diffraction(XRD),fourier transform infrared spectrometer(FT-IR)and other analytical instruments,and the adsorption properties of AMP/SiO_(2) for Cs+in aqueous solution were preliminary investigated.The results showed that AMP was uniformly dispersed in the structure and pores of mesoporous silica,and the composite had a large specific surface area(451.2 m^(2)/g)and pore volume(0.95 cm^(3)/g).In addition,the adsorption process of adsorbent for Cs+was in accord with the pseudo-second-order kinetic model and Freundlich isotherm adsorption model,and the equilibrium adsorption capacity was up to 63.45 mg/g.

关 键 词：硅藻土 磷钼酸铵 二氧化硅 铯 吸附 

分 类 号：TQ127.2[化学工程—无机化工]