Co-tmb骨架材料的合成  

The Synthesis of Co-tmb Frameworks

作　　者：王海鹏 李宝龙[2] 边晓洁 WANG Hai-peng;LI Bao-long;BIAN Xiao-jie(School of Chemistry and Chemical Engineering,Shanxi Datong University,Datong Shanxi,037009;Key Laboratory of Organic Synthesis of Jiangsu Province,Soochow University,Suzhou Jiangsu,215123;School of Chemistry and Chemical Engineering,Qinghai Nationalities University,Xining Qinghai,810007)

机构地区：[1]山西大同大学化学与化工学院,山西大同037009 [2]苏州大学江苏省有机合成重点实验室,江苏苏州215123 [3]青海民族大学化学化工学院,青海西宁810007

出　　处：《山西大同大学学报（自然科学版）》2021年第3期5-6,11,共3页Journal of Shanxi Datong University(Natural Science Edition)

基　　金：国家自然科学基金资助项目[21171126]。

摘　　要：选用新型多齿柔性配体1,3,5-三(三氮唑-1-甲基)苯(tmb)与钴盐和第二配体NaN3通过自组装反应合成了金属有机骨架材料[Co(tmb)2(N3)2]n,对其单晶结构进行表征,表明该材料呈一维双股链结构,并进行了红外和元素分析表征。The metal-organic frameworks[Co(tmb)2(N3)2]n was synthesized by self-assembly reaction of 1,3,5-tri(1,2,4-triazol 1-ylmethyl)benzene(tmb)as the new type flexible ligand and NaN3 as the second ligand with cobalt salt.The structure,IR and ele-mental analysis were characterized respectively,and the framework presented a one-dimensional double chain structure.

关 键 词：1 3 5-三(三氮唑-1-甲基)苯 骨架材料 合成 

分 类 号：O614.7[理学—无机化学]