矿井提升钢丝绳改性氧化石墨烯润滑油减摩特性研究  

Anti-Friction Properties of Modified Graphene Oxide Lubricants for Wire Rope in a Mine Hoist

作　　者：彭玉兴[1,2,3] 王臣 朱真才 唐玮[1,2,3] 王大刚 卢昊[1,2,3] PENG Yuxing;WANG Chen;ZHU Zhencai;TANG Wei;WANG Dagang;LU Hao(School of Mechatronic Engineering,China University of Mining and Technology,Jiangsu Xuzhou 221116,China;Jiangsu Province and Education Ministry Co-sponsored Collaborative Innovation Center of Intelligent Mining Equipment,Jiangsu Xuzhou 221116,China;Jiangsu Key Laboratory of Mine Electromechanical Equipment,Jiangsu Xuzhou 221116,China)

机构地区：[1]中国矿业大学机电工程学院,江苏徐州221116 [2]江苏省矿山智能采掘装备协同创新中心(省部共建),江苏徐州221116 [3]江苏省矿山机电装备重点实验室,江苏徐州221116

出　　处：《摩擦学学报》2021年第2期149-159,共11页Tribology

基　　金：教育部创新团队发展计划(IRT16R68);江苏高校优势学科建设工程项目(PAPD);江苏高校品牌专业建设工程项目(TAPP)资助。

摘　　要：针对恶劣提升工况下润滑失效导致的提升钢丝绳内部钢丝摩擦磨损严重的问题,开展改性氧化石墨烯润滑油减摩特性研究.首先,制备十八胺官能化氧化石墨烯(ODA-GO)及其水合肼还原材料(ODA-rGO),分析其化学结构、表面形貌、片层间距和缺陷,探究其在钢丝绳润滑油IRIS中的分散性;接着,用四球机评价改性润滑油的减摩抗磨性能并研究其润滑机理;最后,评判ODA-GO改性油对钢丝减摩的改进效果.结果表明:ODA通过酰胺化反应和亲核取代反应接枝在GO表面,ODA-GO拥有高接枝密度的十八烷基链,并在IRIS中分散性较好,ODA-rGO则相反,但在最优添加量下ODA-rGO的抗磨减摩性优于ODA-GO;改性石墨烯基材料会附着在摩擦接触表面,并填补已损伤区域,从而减少磨损;ODA-GO改性油使钢丝间摩擦系数降低10%,疲劳磨损显著降低.To solve the serious tribological problem between the internal steel wires of the lifting wire ropes caused by lubrication failure under harsh lifting conditions,the anti-friction properties of modified graphene oxide lubricants were studied.Firstly,octadecylamine functionalized graphene oxide(ODA-GO)and its reduced material by hydrazine hydrate(ODA-rGO)were prepared.Their chemical structure,surface morphology,interlayer spacing and defects were investigated,and their dispersibility in a wire rope lubricant named IRIS was explored.Then,the anti-wear and friction reduction properties of modified oils were evaluated by four-ball machine and the lubrication mechanism was analyzed.Finally,the effect on the friction reduction between wires of ODA-GO lubricant was analyzed.The results showed that ODA was grafted on GO surface through amidation reaction and nucleophilic substitution reaction.ODA-GO had a high grafting density of octadecyl chains with good dispersion in IRIS,while ODA-rGO showed the opposite results.However,the optimal friction reduction and anti-wear properties of ODA-rGO were better than ODA-GO.Besides,the modified graphene-based materials would be adsorbed on the contact surfaces and filled the damaged areas to reduce wear.Furthermore,the ODA-GO lubricant reduced the coefficient of friction of the wires by 10%and reduced the fatigue wear significantly.

关 键 词：提升钢丝绳 改性氧化石墨烯 润滑油 分散稳定性 减摩 

分 类 号：TH117.1[机械工程—机械设计及理论]