BN Fused Diazulenyl-Carbazole:Synthesis,Structure,and Properties  

作　　者：Fang-Dong Zhuang Jing-Hui Yang Ze-Hao Sun Peng-Fei Zhang Qi-Ran Chen Jie-Yu Wang Jian Pei 

机构地区：[1]Beijing National Laboratory for Molecular Sciences,Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education,Center for Soft Matter Science and Engineering,College of Chemistry and Molecular Engineering,Peking University,Beijing,100871 China

出　　处：《Chinese Journal of Chemistry》2021年第4期909-912,共4页中国化学（英文版）

基　　金：This work is supported by the National Key R&D Program of China(No.2017YFA0204701);the National Natural Science Foundation of China(Nos.21722201,21790360).

摘　　要：Main observation and conclusion By combination of two special structural units,a boron-nitrogen-fused polycyclic aromatic hydrocarbon and azulene with strong intramolecular dipoles,a novel BN aromatics,BN-Az,has been designed and synthesized with unique characteristics.The structure,optical and electrochemical properties,as well as charge transport property of BN-Az have been investigated.Notably,BN-Az selectively responds to fluoride ions and protons with a significant color change,which could also be monitored by NMR spectra and single-crystal X-ray analysis,indicating its potential as an effective ion sensing material in stimuli-responsive electronic devices.

关 键 词：Boron-nitrogen AZULENE Sensor Single Crystal Organic field-effect transistors 

分 类 号：O62[理学—有机化学]