A Top-Down Approach towards Cu(I)Alkynyl Clusters with Unusual Geometry  

作　　者：Huan Li Ting Li Shuimiao Liu Mei Qu Linfeng Liang Fengwei Zhang Xian-Ming Zhang 

机构地区：[1]Institute of Crystalline Materials,Shanxi University,Taiyuan,Shanxi,030006 China [2]School of Chemistry and Material Science,Shanxi Normal University,Linfen,Shanxi,041004 China

出　　处：《Chinese Journal of Chemistry》2021年第4期937-941,共5页中国化学（英文版）

基　　金：the National Natural Science Foundation of China(Nos.21972080,21503123,91961201,21871167);1331 project for Featured Chemistry Discipline in Shanxi Normal University.

摘　　要：Main observation and conclusion To search for novel Cu(I)complexes,traditional approaches focus on designing and screening ligands,metal precursors and reaction parameters.In this report,we propose a top-down approach,in which Cu precursor is first reduced to nanoparticles in the presence of alkynyl and phosphine ligands.

关 键 词：Copper TOP-DOWN Cluster FLUORESCENCE ALKYNYL 

分 类 号：O62[理学—有机化学]