Electrochemical synthesis of 3-azido-indolines from amino-azidation of alkenes  

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作  者:Shengping Guo Liyan Liu Kangfei Hu Qi Sun Zhenggen Zha Yu Yang Zhiyong Wang 

机构地区:[1]Hefei National Laboratory for Physical Sciences at Microscale,CAS Key Laboratory of Soft Matter Chemistry&Center for Excellence in Molecular Synthesis of Chinese Academy of Sciences,Collaborative Innovation Center of Suzhou Nano Science and Technology&School of Chemistry and Materials Science,University of Science and Technology of China,Hefei 230026,China [2]School of Chemistry and Chemical Engineering,Hefei Normol University,Hefei 230601,China

出  处:《Chinese Chemical Letters》2021年第3期1033-1036,共4页中国化学快报(英文版)

基  金:financial support from the National Natural Science Foundation of China(Nos.21672200,21772185,21801233);the assistance of the product characterization from the Chemistry Experiment Teaching Center of University of Science and Technology of China;supported by China Postdoctoral Science Foundation(No.2018M632532);the Strategic Priority Research Program of the Chinese Academy of Sciences(No.XDB20000000)。

摘  要:An electrochemical amino-azidation of 2-aminostyre ne with sodium azide(NaN3)was developed,which can be carried out smoothly in water under metal-free condition,affording a series of 3-azido indolines with high yields.

关 键 词:ELECTROCHEMICAL Amino-azidation 2-Amino styrene Metal-free Oxidant-free 3-Azido indolines 

分 类 号:O626.13[理学—有机化学]

 

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