不对称酰胺基二茂铁卟啉的合成及其性能研究  

Synthesis and performance of unsymmetrical amido ferrocene porphyrins

作　　者：崔旭 张听雨 王瑛 李雪梅 张加研 庄长福 CUI Xu;ZHANG Ting-yu;WANG Ying;LI Xue-mei;ZHANG Jia-yan;ZHUANG Chang-fu(College of Chemical Engineering,Southwest Forestry University,Kunming 650224,China)

机构地区：[1]西南林业大学化学工程学院,云南昆明650224

出　　处：《化学研究与应用》2021年第6期1082-1087,共6页Chemical Research and Application

基　　金：国家自然科学基金项目(31760190,31960296)资助;云南省科技厅农业联合专项项目(2017FG001026,2017FG001055,2018FG001058)资助。

摘　　要：合成了两种不对称酰胺基二茂铁卟啉化合物,利用质谱、核磁共振氢谱、紫外光谱和红外光谱等方法表征了其结构,并讨论了酰胺基二茂铁卟啉的荧光,电化学,拉曼光谱的影响和变化规律。光谱和电化学的研究表明,取代基(CH_(3)O)使酰胺基二茂铁卟啉发射光谱红移,荧光量子产率增大,对于拉曼光谱的苯环振动有很大的影响;电化学结果显示使卟啉更易失电子被氧化。研究结果表明通过改变卟啉周边的取代基可以调控二茂铁卟啉的光谱和电化学性能.In this paper,two unsymmetrical imide ferrocene porphyrins were designed and synthesized.Porphyrins’s structures were characterized by GC,IR,1H NMR and UV-Vis spectra,and the effects of fluorescence,electrochemical and Raman spectra of ferrocene porphyrins were discussed.The results of spectroscopic and electrochemical studies showed that the substituents(CH_(3)O)caused the red shift of emission spectra and the increase of fluorescence quantum yield.The results showed that the spectra and electrochemical properties of ferrocene porphyrins could be affected by controlling the different substituents around porphyrins.

关 键 词：二茂铁卟啉 合成 光谱 电化学 

分 类 号：O614[理学—无机化学]