N-烷基胺类作为多功能砌块在氧化偶联反应中的应用  

Application of N-Alkyl Amines as Versatile Building Blocks in Oxidative Coupling Reactions

作　　者：陈缘 夏立静 常怡婷 马武珍 王彬[1] Chen Yuan;Xia Lijing;Chang Yiting;Ma Wuzhen;Wang Bin(College of Pharmacy,Nankai University,Tianjin 300353)

机构地区：[1]南开大学药学院,天津300353

出　　处：《有机化学》2021年第5期1851-1877,共27页Chinese Journal of Organic Chemistry

基　　金：天津市科学技术委员会(No.19JCTPJC48400);国家大学生创新(No.201910055456)资助项目.

摘　　要：N-烷基胺的氧化官能团化是形成碳-碳键和碳-杂原子键的最直接和通用的策略之一.近年来,N-烷基胺类作为多功能砌块在交叉脱氢偶联(CDC)反应中取得了长足发展.基于N-烷基胺的不同角色,总结了近年来它们在氧化偶联反应中的应用进展.The oxidative functionalization of N-alkylamines is one of the most direct and versatile strategies for the formation of C—C and C-heteroatom bonds.In recent years,N-alkylamines as multifunctional blocks have made great progress in crossdehydrogenation-coupling(CDC)reactions.The recent progress in the application of N-alkylamines is summarized on the basis of different roles in oxidative coupling reactions.

关 键 词：N-烷基胺 N N-二甲基苯胺 四氢异喹啉 交叉脱氢偶联反应 

分 类 号：O621.25[理学—有机化学]