糠醛及其衍生物选择性加氢制备戊二醇的研究进展  

Recent advances in the selective hydrogenation of furfural and its derivatives to pentanediol

作　　者：谭静静 苏以豪 高宽 崔静磊 王永钊[1] 赵永祥[1] TAN Jing-jing;SU Yi-hao;GAO Kuan;CUI Jing-lei;WANG Yong-zhao;ZHAO Yong-xiang(Engineering Research Center of Ministry of Education for Fine Chemicals,School of Chemistry and Chemical Engineering,Shanxi University,Taiyuan 030006,China;Institute of Resources and Environmental Engineering,Shanxi University,Taiyuan 030006,China)

机构地区：[1]山西大学化学化工学院精细化学品教育部工程研究中心,山西太原030006 [2]山西大学资源与环境工程研究所,山西太原030006

出　　处：《燃料化学学报》2021年第6期780-790,共11页Journal of Fuel Chemistry and Technology

基　　金：国家自然科学基金(22005182,21703275,U1710221);山西省高等学校科技创新项目(2020L0012);山西省面上青年基金(201701D221030)资助。

摘　　要：1,2-戊二醇(1,2-PeD)和1,5-戊二醇(1,5-PeD)是高附加值精细化学品,用途广泛。以糠醛及其衍生物为原料经催化加氢制备1,2-PeD和1,5-PeD是绿色的生产工艺,具有良好的应用前景和研究价值。本文系统综述了国内外以糠醛及其衍生物糠醇、四氢糠醇为原料制备1,2-PeD和1,5-PeD的研究现状,重点总结了应用于糠醛、糠醇和四氢糠醇催化加氢制备1,2-PeD和1,5-PeD的催化剂,从催化剂类型、不同催化体系辅助酸/碱催化反应机理、活性金属与掺杂过渡金属氧化物间的协同催化、掺杂过渡金属氧化物的酸性以及不同催化体系中催化剂的构效关系等方面进行了详细阐述,并在此基础上对该研究方向的发展趋势进行了展望。为开发新型、高效、稳定催化糠醛及其衍生物加氢催化剂体系提供了理论指导和有益的借鉴。1,2-pentanediol(1,2-PeD)and 1,5-pentanediol(1,5-PeD)are high-value fine chemicals with a wide range of uses.It is a green process with well application prospects and research value for the preparation of 1,2-PeD and 1,5-PeD from furfural and its derivatives.Here,the recent advances of furfural and its derivatives furfuryl alcohol and tetrahydrofurfuryl alcohol in the synthesis of 1,2-PeD and 1,5-PeD were reviewed systematically.We focused on the summary of the catalysts used in the catalytic hydrogenation of furfural,furfuryl alcohol and tetrahydrofurfuryl alcohol to prepare 1,2-PeD and 1,5-PeD.The design and application of the catalysts were elaborated from many aspects,including the catalyst type,the reaction mechanism with assist acid/base in different catalytic systems,the synergistic catalysis between active metals and doped transition metal oxides,the influence of acidity of doped transition metal oxides in the catalyst,the structure-activity relationships and so on.On this basis,the development trend of this research direction is prospected.It provides the theoretical guidance and useful reference for developing a new,efficient and stable catalyst system for the hydrogenation of furfural and its derivatives.

关 键 词：糠醛 糠醇 四氢糠醇 催化加氢 1 2-戊二醇 1 5-戊二醇 

分 类 号：O643.3[理学—物理化学]