NMR在含氟内酯类化合物反应机理研究中的应用  

APPLICATION OF NMR IN STUDYING THE MECHANISM OF CHEMICAL REACTIONS INVOLVING FLUORINE-CONTAINING LACTONES

作　　者：周丽芳[1] 潘铁英[1] 史新梅[1] 贺彩霞[1] 邹小卫[2] 吴范宏[2] 

机构地区：[1]华东理工大学分析测试中心 [2]华东理工大学精细化工研究所,上海200237

出　　处：《波谱学杂志》2002年第4期401-408,共8页Chinese Journal of Magnetic Resonance

摘　　要：运用NMR核磁共振谱对 3种含氟内酯化合物的结构进行确认 ,尤其是运用NOESY谱确定了该类化合物的空间构型 ,为反应机理的研究提供了强有力的依据 .The fluorine-containing lactones are often present in natural organic compounds. In this study the structures of three fluorine-containing lactones were determined using the NMR techniques(1H NMR, {13\}C NMR, 1H-1H COSY,NOESY,HMBC,HMQC). Two-dimensional NOESY was especially useful for providing information on the stereo configuration of the compounds. Knowing the structures can be helpful in studying the mechanism of chemical reactions involving fluorine-containing lactones.

关 键 词：NMR 含氟内酯化合物 空间构型 反应机理 结构测定 核磁共振谱 

分 类 号：O628.51[理学—有机化学] O621[理学—化学]