Analysis of the microstructure of superconducting YBCO foams by means of AFM and EBSD  

作　　者：Michael Rudolf KOBLISCHKA Anjela KOBLISCHKA-VENEVA E.S.REDDY Gregor J.SCHMITZ 

机构地区：[1]Institute of Experimental Physics,Saarland University,P.O.Box 151150,D-66041 Saarbrücken,Germany [2]ACCESS,Intzestrasse 5,52072 Aachen,Germany [3]Nanonouvelle Pty Ltd.,Marcoola QLD 4564,Australia

出　　处：《Journal of Advanced Ceramics》2014年第4期317-325,共9页先进陶瓷（英文）

基　　金：We acknowledge collaborations within the European Forum for Processors of Bulk Superconductors(EFFORT),which is funded by the Engineering and Physical Sciences Research Council(EPSRC)of the UK government.

摘　　要：YBa_(2)Cu_(3)O_(y)(YBCO)foam samples show an open,porous foam structure,which may have benefits for many applications of high-Tc superconductors.As the basic material of these foams is a pseudo-single crystalline material with the directional growth initiated by a seed crystal similar to standard melt-textured samples,the texture of YBCO is a very important parameter.Therefore,we analysed the local texture and grain orientation of the individual struts forming the foam by means of atomic force microscopy(AFM)and electron backscatter diffraction(EBSD).Due to the processing route starting with Y_(2)BaCuO_(5)(211),a two-phase analysis must be performed,so a high surface quality is necessary to enable an automated EBSD scan.Good quality Kikuchi patterns were obtained from both the YBCO and 211 phases.We found an inhomogeneous distribution of the residual 211 particles,which are mainly randomly oriented and have sizes ranging between 200 nm and 15μm.In contrast to this,the YBCO matrix shows a dominating orientation with cracks with a typical distance of 1-10μm.Furthermore,the analysis of strut cross-sections reveals that the entire strut is converted to the YBCO phase.

关 键 词：high-Tc superconductors foam MICROSTRUCTURE atomic force microscopy(AFM) electron backscatter diffraction(EBSD) orientation 

分 类 号：TG1[金属学及工艺—金属学]