功能高分子增韧改性POM复合材料的研究进展  

Research progress of POM composites toughening-modified by functional polymers

作　　者：方伟 范晓东[1] 黄河 金政伟 袁炜 Fang Wei;Fan Xiaodong;Huang He;Jin Zhengwei;Yuan Wei(School of Natural and Applied Science,Northwestern Polytechnical University,Xi′an 710129,China;Coal Chemical Technology Research Institute of Ningxia Coal Industry Co.,Ltd.,China Energy Group,Yinchuan 750011,China)

机构地区：[1]西北工业大学理学院,陕西西安710129 [2]国家能源集团宁夏煤业公司煤炭化学工业技术研究院,宁夏银川750011

出　　处：《合成树脂及塑料》2021年第4期71-75,共5页China Synthetic Resin and Plastics

基　　金：宁夏回族自治区2018重点研发计划项目(2018BDE02040)。

摘　　要：综述了国内外聚甲醛(POM)功能化改性方面的研究进展,如热塑性聚氨酯改性POM中引入马来酸酐接枝氢化苯乙烯-丁二烯-苯乙烯嵌段共聚物或环氧化多官能团扩链剂,可改善二者相容性;添加包覆型无卤阻燃剂可提高POM的阻燃性;采用聚乳酸改性POM,可以改善POM的结晶形态,形成互穿网络;利用具有抗紫外光老化性能的丙烯酸酯弹性体改性POM,制备的复合材料既具有抗紫外光老化性能,又具有较好的韧性。除上述研究外,POM改性还应广泛选取其他性能优异的工程塑料或特殊结构的功能高分子来拓宽研究思路,如采用具有特殊结构的聚酯弹性体对POM进行协同改性,或采用动态硫化技术制备基于POM的热塑性动态硫化弹性体。The research progresses of functionalized modification for polyformaldehyde(POM)in China and overseas are reviewed,which include introducing maleic anhydride grafted hydro styrene-butadiene-styrene block copolymer(SEBS-g-MA)or epoxide multifunctional chain-extender to thermal polyurethane modified POM to improve their compatibility,adding coated halogen-free flame retardants to improve the flame retardancy of POM,modifying POM by polyactic acid(PLA)to improve the crystal morphology and form interpenetrating network structure of PLA/POM blends,and modifying POM by acrylate elastomers to improve the anti-ultraviolet aging properties and toughness of the composites.In addition,other excellent engineering plastics or functional polymers with special structures should be selected to broaden the research field,such as polyester elastomers with special structures for POM synergistic modification,or thermal dynamic vulcanized elastomer based on POM by dynamic vulcanization technology.

关 键 词：聚甲醛 增韧改性 功能高分子 复合材料 

分 类 号：TQ322.3[化学工程—合成树脂塑料工业]